Two Cu-2 and Zn-2 metallamacrocycles featuring a novel extended pi-conjugated carbazole bridge
文献类型：期刊论文
| 作者 | A. R. Paital ; A. Q. Wu ; G. C. Guo ; G. Aromi ; J. Ribas-Arino ; D. Ray |
| 刊名 | Inorganic Chemistry
 |
| 出版日期 | 2007-04 |
| 卷号 | 46期号:8页码:2947-2949 |
| 关键词 | exchange-coupling-constant spin ground-state magnetostructural correlations copper(ii) complex polarization chemistry dimers angle |
| ISSN号 | 0020-1669 |
| 中文摘要 | Two neutral dinuclear metallamacrocycles, [Cu-2(hbca)(2)]center dot 2CHCl(3)center dot 2H(2)O (1) and [Zn-2(hbca)(2)]center dot 7H(2)O (2), have been assembled from reactions of the new rigid carbazole-based ligand H(2)hbca [N,N'-bis(2-hydroxobenzylidene)-9H-carbazole-3,6-diamine] with copper(II) or zinc(II) acetate. The extended aromatic ligand spacer is responsible for intermetallic antiferromagnetic exchange, which is rationalized using the spin-polarization formalism with the help of density functional theory calculations. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6547]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | A. R. Paital,A. Q. Wu,G. C. Guo,et al. Two Cu-2 and Zn-2 metallamacrocycles featuring a novel extended pi-conjugated carbazole bridge[J]. Inorganic Chemistry,2007,46(8):2947-2949. |
| APA | A. R. Paital,A. Q. Wu,G. C. Guo,G. Aromi,J. Ribas-Arino,&D. Ray.(2007).Two Cu-2 and Zn-2 metallamacrocycles featuring a novel extended pi-conjugated carbazole bridge.Inorganic Chemistry,46(8),2947-2949. |
| MLA | A. R. Paital,et al."Two Cu-2 and Zn-2 metallamacrocycles featuring a novel extended pi-conjugated carbazole bridge".Inorganic Chemistry 46.8(2007):2947-2949. |
入库方式： OAI收割
来源：福建物质结构研究所
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