Single-crystal structure and magnetic behavior of a molecule-based ferrimagnet Mn Mn0.2Cr0.8(CN)(6) center dot 4H(2)O
文献类型：期刊论文
| 作者 | X. P. Shen ; Y. Z. Li ; Y. Song ; Z. Xu ; G. C. Guo |
| 刊名 | European Journal of Inorganic Chemistry
 |
| 出版日期 | 2007-04 |
| 期号 | 12页码:1698-1702 |
| 关键词 | Prussian blue analogue crystal structure magnetic properties chromium manganese prussian blue analogs high-spin molecules building-blocks ground-state complexes cluster cyanide temperature manganese ethylenediamine |
| ISSN号 | 1434-1948 |
| 中文摘要 | The compound with the stoichiometry Mn-III[Mn(III)0.2Cr(III)0.8-(CN)(6)]center dot 4H(2)O (1), which was prepared by slow diffusion of an aqueous solution of K-3[Cr(CN)(6)] and a methanol solution of [Mn(saltn)]ClO4 [saltn = N,N'-1,3-propylenebis(sahcylidene-iminato) dianion] through a U-shaped tube containing silica gel, has been characterized by elemental analysis, ICP analysis, XPS, single-crystal X-ray structure analysis, and magnetic measurements. The complex has a face-centered cubic lattice analogous to Prussian blue and indicates ferrimagnetic ordering below T-c = 63 K. (C) Wiley-VCH Verlag GmbH & Co. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6587]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | X. P. Shen,Y. Z. Li,Y. Song,et al. Single-crystal structure and magnetic behavior of a molecule-based ferrimagnet Mn Mn0.2Cr0.8(CN)(6) center dot 4H(2)O[J]. European Journal of Inorganic Chemistry,2007(12):1698-1702. |
| APA | X. P. Shen,Y. Z. Li,Y. Song,Z. Xu,&G. C. Guo.(2007).Single-crystal structure and magnetic behavior of a molecule-based ferrimagnet Mn Mn0.2Cr0.8(CN)(6) center dot 4H(2)O.European Journal of Inorganic Chemistry(12),1698-1702. |
| MLA | X. P. Shen,et al."Single-crystal structure and magnetic behavior of a molecule-based ferrimagnet Mn Mn0.2Cr0.8(CN)(6) center dot 4H(2)O".European Journal of Inorganic Chemistry .12(2007):1698-1702. |
入库方式： OAI收割
来源：福建物质结构研究所
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