中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Single-crystal structure and magnetic behavior of a molecule-based ferrimagnet Mn Mn0.2Cr0.8(CN)(6) center dot 4H(2)O

文献类型:期刊论文

作者X. P. Shen ; Y. Z. Li ; Y. Song ; Z. Xu ; G. C. Guo
刊名European Journal of Inorganic Chemistry
出版日期2007-04
期号12页码:1698-1702
关键词Prussian blue analogue crystal structure magnetic properties chromium manganese prussian blue analogs high-spin molecules building-blocks ground-state complexes cluster cyanide temperature manganese ethylenediamine
ISSN号1434-1948
中文摘要The compound with the stoichiometry Mn-III[Mn(III)0.2Cr(III)0.8-(CN)(6)]center dot 4H(2)O (1), which was prepared by slow diffusion of an aqueous solution of K-3[Cr(CN)(6)] and a methanol solution of [Mn(saltn)]ClO4 [saltn = N,N'-1,3-propylenebis(sahcylidene-iminato) dianion] through a U-shaped tube containing silica gel, has been characterized by elemental analysis, ICP analysis, XPS, single-crystal X-ray structure analysis, and magnetic measurements. The complex has a face-centered cubic lattice analogous to Prussian blue and indicates ferrimagnetic ordering below T-c = 63 K. (C) Wiley-VCH Verlag GmbH & Co.
语种英语
公开日期2013-04-01
源URL[http://ir.fjirsm.ac.cn/handle/350002/6587]  
专题福建物质结构研究所_中科院福建物质结构研究所_期刊论文
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X. P. Shen,Y. Z. Li,Y. Song,et al. Single-crystal structure and magnetic behavior of a molecule-based ferrimagnet Mn Mn0.2Cr0.8(CN)(6) center dot 4H(2)O[J]. European Journal of Inorganic Chemistry,2007(12):1698-1702.
APA X. P. Shen,Y. Z. Li,Y. Song,Z. Xu,&G. C. Guo.(2007).Single-crystal structure and magnetic behavior of a molecule-based ferrimagnet Mn Mn0.2Cr0.8(CN)(6) center dot 4H(2)O.European Journal of Inorganic Chemistry(12),1698-1702.
MLA X. P. Shen,et al."Single-crystal structure and magnetic behavior of a molecule-based ferrimagnet Mn Mn0.2Cr0.8(CN)(6) center dot 4H(2)O".European Journal of Inorganic Chemistry .12(2007):1698-1702.

入库方式: OAI收割

来源:福建物质结构研究所

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