Synthesis, structure and fluorescent property of a novel 2-D sheet inorganic-organic hybrid cadmium polymer CdBr2(bpdo) (n)
文献类型:期刊论文
作者 | Y. C. Shen ; P. X. Yin ; Z. J. Li ; Y. Y. Qin ; Y. G. Yao |
刊名 | Chinese Journal of Structural Chemistry
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出版日期 | 2007 |
卷号 | 26期号:11页码:1345-1348 |
关键词 | cadmium polymer bpdo crystal structure luminescence crystal-structures n-oxide |
ISSN号 | 0254-5861 |
中文摘要 | A novel 2-D sheet inorganic-organic hybrid cadmiuni polymer, [CdBr2(bpdo)](n) (bpdo = N,N'-O,O-4,4'-bipyridine) has been hydrothermally synthesized and characterized by elemental analysis, IR and single-crystal X-ray diffraction. The crystal crystallizes in monoclinic, space group C2/c, with a = 16.336(3), b = 3.9904(5), c = 18.479(3) angstrom, beta = 91.640(6)degrees, M-r = 460.40, V = 1204.1(3) angstrom(3), Z = 4, D-c = 2.540 g/cm(3), mu = 8.439 mm(-1), F(000) = 864, R = 0.0314 and wR = 0.0733 for 1069 observed reflections (I > 2 sigma(I)). X-ray diffraction reveals that the title compound consists of the 2-D inorganic-organic hybrid sheet constructed from [CdBr2],, chains and bpdo bridges in the packing motif of ...ABAB.... The title compound exhibits intense blue photoluniinescence in the solid state at room temperature. |
语种 | 英语 |
公开日期 | 2013-04-01 |
源URL | [http://ir.fjirsm.ac.cn/handle/350002/6592] ![]() |
专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
推荐引用方式 GB/T 7714 | Y. C. Shen,P. X. Yin,Z. J. Li,et al. Synthesis, structure and fluorescent property of a novel 2-D sheet inorganic-organic hybrid cadmium polymer CdBr2(bpdo) (n)[J]. Chinese Journal of Structural Chemistry,2007,26(11):1345-1348. |
APA | Y. C. Shen,P. X. Yin,Z. J. Li,Y. Y. Qin,&Y. G. Yao.(2007).Synthesis, structure and fluorescent property of a novel 2-D sheet inorganic-organic hybrid cadmium polymer CdBr2(bpdo) (n).Chinese Journal of Structural Chemistry,26(11),1345-1348. |
MLA | Y. C. Shen,et al."Synthesis, structure and fluorescent property of a novel 2-D sheet inorganic-organic hybrid cadmium polymer CdBr2(bpdo) (n)".Chinese Journal of Structural Chemistry 26.11(2007):1345-1348. |
入库方式: OAI收割
来源:福建物质结构研究所
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