Synthesis and crystal structure of Cd(NBA)(mu(3)-OH)(4,4 '-bipy)(1/2) (n)
文献类型：期刊论文
| 作者 | Y. C. Shen ; J. Zhang ; Z. J. Li ; L. Zhang ; P. X. Yin ; Y. G. Yao |
| 刊名 | Chinese Journal of Structural Chemistry
 |
| 出版日期 | 2007 |
| 卷号 | 26期号:8页码:917-919 |
| 关键词 | cadmium polymer 4 4 '-bipyridine m-nitrobenzoic acid crystal structure hydrothermal synthesis |
| ISSN号 | 0254-5861 |
| 中文摘要 | A new cadmium polymer [Cd(NBA)(mu(3)-OH)(4,4'-bipy)1/2](n) 1 (NBA = m-nitrobenzoic acid and 4,4'-bipy = 4,4-bipyridine) has been synthesized by hydrothermal reaction. Its structure was determined by single-crystal X-ray diffraction method, and characterized by elemental analysis and IR spectrum. The crystal is of monoclinic, space group C2/c, with a = 15.6912(9), b = 25.9394(15), c = 6.7332(4) angstrom, beta = 114.7700(10)degrees, V = 2488.4(3) angstrom(3), C12H9CdN2O5, M-r = 373.61, Z = 8, D-c = 1.995 g/cm(3), mu = 1.776 mm(-1), F(000) = 1464, R = 0.0411 and wR = 0.1128 for 2130 observed reflections (I > 2 sigma(I)). X-ray diffraction studies reveal that the compound features a layered structure, in which 4,4'-bipy ligands bridge Z type of double chains [Cd(mu(3)-OH)](n) and NBA ligands locate at the two sides of the layer. The pi-pi interactions between the benzene rings of NBA ligands of two adjacent layers lead to the 3D framework. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6595]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | Y. C. Shen,J. Zhang,Z. J. Li,et al. Synthesis and crystal structure of Cd(NBA)(mu(3)-OH)(4,4 '-bipy)(1/2) (n)[J]. Chinese Journal of Structural Chemistry,2007,26(8):917-919. |
| APA | Y. C. Shen,J. Zhang,Z. J. Li,L. Zhang,P. X. Yin,&Y. G. Yao.(2007).Synthesis and crystal structure of Cd(NBA)(mu(3)-OH)(4,4 '-bipy)(1/2) (n).Chinese Journal of Structural Chemistry,26(8),917-919. |
| MLA | Y. C. Shen,et al."Synthesis and crystal structure of Cd(NBA)(mu(3)-OH)(4,4 '-bipy)(1/2) (n)".Chinese Journal of Structural Chemistry 26.8(2007):917-919. |
入库方式： OAI收割
来源：福建物质结构研究所
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