(N-CnH2n-1)-1,3-Azapropanedithiolate (n=5, 6, 7)-bridged diiron complexes as mimics for the active site of FeFe -hydrogenases: the influence of the bridge on the diiron complex
文献类型：期刊论文
| 作者 | Y. T. Si ; C. B. Ma ; M. Q. Hu ; H. Chen ; C. N. Chen ; Q. T. Liu |
| 刊名 | New Journal of Chemistry
 |
| 出版日期 | 2007 |
| 卷号 | 31期号:8页码:1448-1454 |
| 关键词 | fe-only hydrogenases iron hydrogenase crystal-structure model chemistry coordination evolution cluster |
| ISSN号 | 1144-0546 |
| 中文摘要 | To further understand the e. ects of 1,3- azadithiolate (ADT) bridges on the structures and properties of diiron complexes, a novel family of (N- CnH2n - 1)- 1,3- azapropanedithiolate- bridged diiron complexes [Fe-2( CO) (6)( CH2S) N-2 - CnH(2n) - 1] (n = 5, 6, 7) and their PMe3- disubstituted complexes [Fe-2(CO) (4)( PMe3) (2)( CH2S) N-2 - CnH(2)n - 1] (n = 5, 6, 7) were synthesized as mimics of [ FeFe]- hydrogenases. Our studies suggest that the coordination con. gurations, CO stretching frequencies, (1) H and (31) P NMR signals, redox potentials and electrocatalytic H-2- production processes of diiron complexes are closely pertinent to the electron- donating abilities and steric chemistry of the ADT bridges. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6599]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | Y. T. Si,C. B. Ma,M. Q. Hu,et al. (N-CnH2n-1)-1,3-Azapropanedithiolate (n=5, 6, 7)-bridged diiron complexes as mimics for the active site of FeFe -hydrogenases: the influence of the bridge on the diiron complex[J]. New Journal of Chemistry,2007,31(8):1448-1454. |
| APA | Y. T. Si,C. B. Ma,M. Q. Hu,H. Chen,C. N. Chen,&Q. T. Liu.(2007).(N-CnH2n-1)-1,3-Azapropanedithiolate (n=5, 6, 7)-bridged diiron complexes as mimics for the active site of FeFe -hydrogenases: the influence of the bridge on the diiron complex.New Journal of Chemistry,31(8),1448-1454. |
| MLA | Y. T. Si,et al."(N-CnH2n-1)-1,3-Azapropanedithiolate (n=5, 6, 7)-bridged diiron complexes as mimics for the active site of FeFe -hydrogenases: the influence of the bridge on the diiron complex".New Journal of Chemistry 31.8(2007):1448-1454. |
入库方式： OAI收割
来源：福建物质结构研究所
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