Effect of deprotonation of a benzimidazolyl ligand on the redox potential and the structures of mononuclear ruthenium(II) complexes
文献类型:期刊论文
作者 | H. F. Sun ; M. Wang ; K. Jin ; C. B. Ma ; R. Zhang ; L. C. Sun |
刊名 | European Journal of Inorganic Chemistry
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出版日期 | 2007-09 |
期号 | 26页码:4128-4131 |
关键词 | benzimidazolyl ligand pyrazole-3 redox switch 5-bis(benzimidazole) reversible protonation and deprotonation Ru-II complex cytochrome-c-oxidase dinuclear ruthenium photophysical properties spectroscopic properties isomeric complexes crystal-structure oxidation state acid |
ISSN号 | 1434-1948 |
中文摘要 | A monoruthenium(II) complex of the benzimidazolyl ligand and its deprotonated counterpart were prepared and structurally characterized. The reversible protonation/deprotonation process of the ancillary ligand switches the redox potential of the ruthenium(II) core from 0.69 to 0.26 V vs. Ag/AgNO3. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007) |
语种 | 英语 |
公开日期 | 2013-04-01 |
源URL | [http://ir.fjirsm.ac.cn/handle/350002/6615] ![]() |
专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
推荐引用方式 GB/T 7714 | H. F. Sun,M. Wang,K. Jin,et al. Effect of deprotonation of a benzimidazolyl ligand on the redox potential and the structures of mononuclear ruthenium(II) complexes[J]. European Journal of Inorganic Chemistry,2007(26):4128-4131. |
APA | H. F. Sun,M. Wang,K. Jin,C. B. Ma,R. Zhang,&L. C. Sun.(2007).Effect of deprotonation of a benzimidazolyl ligand on the redox potential and the structures of mononuclear ruthenium(II) complexes.European Journal of Inorganic Chemistry(26),4128-4131. |
MLA | H. F. Sun,et al."Effect of deprotonation of a benzimidazolyl ligand on the redox potential and the structures of mononuclear ruthenium(II) complexes".European Journal of Inorganic Chemistry .26(2007):4128-4131. |
入库方式: OAI收割
来源:福建物质结构研究所
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