2D correlation spectral study of a coordination polymer Eu(PCPOA)(3)(H2O) (n)
文献类型：期刊论文
| 作者 | R. Q. Sun ; H. H. Zhang ; Y. N. Cao ; Y. P. Chen ; Q. Y. Yang ; Z. Y. Wang |
| 刊名 | Spectroscopy and Spectral Analysis
 |
| 出版日期 | 2007-05 |
| 卷号 | 27期号:5页码:842-845 |
| 关键词 | coordination polymer Europium ion two dimensional spectral quantum chemistry calculation correlation infrared-spectroscopy crystal-structure compound |
| ISSN号 | 1000-0593 |
| 中文摘要 | A novel two dimensional coordination polymer [Eu(PCPOA)(3) (H2O)](n) was synthesized under hydrothermal condition. Based on the determination of the structure, the 2D correlation FTIR spectra with the perturbation of magnetism and the 2D correlation fluorescence spectra with the perturbation of temperature were investigated. The energy bonds were calculated using CASTEP Program of Material studio. The Europium ions are nine-coordinated and the ligands adopted two different modes to connect the Eu3+ ions to 2D layer structure. The study of the 2D-FTIR reveals that the carboxylates coordinate with the center ions not only as monodentate, but also as bidentate chelate. The 2D fluorescence spectra indicates that the transition of D-5(0) -> F-7(2) is influenced intensively by the perturbation of temperature. |
| 语种 | 中文 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6620]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | R. Q. Sun,H. H. Zhang,Y. N. Cao,et al. 2D correlation spectral study of a coordination polymer Eu(PCPOA)(3)(H2O) (n)[J]. Spectroscopy and Spectral Analysis,2007,27(5):842-845. |
| APA | R. Q. Sun,H. H. Zhang,Y. N. Cao,Y. P. Chen,Q. Y. Yang,&Z. Y. Wang.(2007).2D correlation spectral study of a coordination polymer Eu(PCPOA)(3)(H2O) (n).Spectroscopy and Spectral Analysis,27(5),842-845. |
| MLA | R. Q. Sun,et al."2D correlation spectral study of a coordination polymer Eu(PCPOA)(3)(H2O) (n)".Spectroscopy and Spectral Analysis 27.5(2007):842-845. |
入库方式： OAI收割
来源：福建物质结构研究所
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