Synthesis, structure and optical properties of cerium(III) triphosphate CeP3O9
文献类型：期刊论文
| 作者 | H. N. Tong ; H. Zhang ; W. D. Cheng ; D. S. Wu ; Y. J. Gong ; J. Zhu ; S. P. Huang ; D. Zhao |
| 刊名 | Chinese Journal of Structural Chemistry
 |
| 出版日期 | 2007 |
| 卷号 | 26期号:3页码:338-346 |
| 关键词 | crystal structure phosphate optical properties density of states crystal-structure magnetic-properties ce3+ ions metaphosphate phosphate ultraphosphate praseodymium luminescence lanthanum ndp5o14 |
| ISSN号 | 0254-5861 |
| 中文摘要 | The single crystal and crystallized powder of triphosphate CeP3O9 have been synthesized, and the space group of CeP3O9 has been determined to be C222(1) with the cell parameters of a = 8.6059, b = 11.2437, c = 7.3518 angstrom, V = 711.4(3) angstrom(3), Z = 4, D-c = 3.520 g/cm(3), F(000) = 700, R = 0.0377 and wR = 0.0930. The absorption and emission spectra have been measured, for which the strongest absorption and emission peaks are located at 280 and 320 nm, respectively. The density of state (DOS) and dielectric function have been calculated by the DFT method. The crystal is transparent provided the wavelength is larger than 341 nm, and the observed ultraviolet cut-off edge is at about 350 nm for a polycrystalline power-sample. It is possible that the triphosphate CeP3O9 will become an ultraviolet emission material. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6635]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | H. N. Tong,H. Zhang,W. D. Cheng,et al. Synthesis, structure and optical properties of cerium(III) triphosphate CeP3O9[J]. Chinese Journal of Structural Chemistry,2007,26(3):338-346. |
| APA | H. N. Tong.,H. Zhang.,W. D. Cheng.,D. S. Wu.,Y. J. Gong.,...&D. Zhao.(2007).Synthesis, structure and optical properties of cerium(III) triphosphate CeP3O9.Chinese Journal of Structural Chemistry,26(3),338-346. |
| MLA | H. N. Tong,et al."Synthesis, structure and optical properties of cerium(III) triphosphate CeP3O9".Chinese Journal of Structural Chemistry 26.3(2007):338-346. |
入库方式： OAI收割
来源：福建物质结构研究所
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