An open-framework cobalt molybdate possessing {Mo2O7} building block: hydrothermal synthesis and structural characterization of CoMo2O7(4,4'-bipy)1.5
文献类型:期刊论文
作者 | C. M. Wang ; Y. Q. Sun ; G. Y. Yang |
刊名 | Journal of Coordination Chemistry
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出版日期 | 2007 |
卷号 | 60期号:22-24页码:2629-2636 |
关键词 | hydrothermal synthesis crystal structure open-frarmework cobalt molybdate state coordination chemistry molybdenum oxide structures solids subunits vanadium ni co |
ISSN号 | 0095-8972 |
中文摘要 | The hydrothermal reaction of CO(COO)(2)center dot 4H(2)O, MoO3, H3PO4 and 4,4'-bipyridine yields bipyridine-ligated cobalt dimolybdate [CoMo2O7(4,4'-bipy)(1.5)] (1) (4,4'-bipy=4,4'-bipyridine) in the triclinic system with space group of Pi and cell parameters of a=71951(8)angstrom, b=11.1708(17)angstrom, c=11.4514(11)angstrom, alpha = 98.545(7)degrees, beta = 90.315(2)degrees, gamma = 105.777(5)degrees, V = 874.88(19) angstrom(3), and Z = 2. Its structure consists of Co/Mo/O bimetal oxide layers with {Mo2O7} building blocks, linked by the coordination of 4,4'-bipy ligand with Co and Mo atoms, into a 3D porous hybrid framework. |
语种 | 英语 |
公开日期 | 2013-04-01 |
源URL | [http://ir.fjirsm.ac.cn/handle/350002/6638] ![]() |
专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
推荐引用方式 GB/T 7714 | C. M. Wang,Y. Q. Sun,G. Y. Yang. An open-framework cobalt molybdate possessing {Mo2O7} building block: hydrothermal synthesis and structural characterization of CoMo2O7(4,4'-bipy)1.5[J]. Journal of Coordination Chemistry,2007,60(22-24):2629-2636. |
APA | C. M. Wang,Y. Q. Sun,&G. Y. Yang.(2007).An open-framework cobalt molybdate possessing {Mo2O7} building block: hydrothermal synthesis and structural characterization of CoMo2O7(4,4'-bipy)1.5.Journal of Coordination Chemistry,60(22-24),2629-2636. |
MLA | C. M. Wang,et al."An open-framework cobalt molybdate possessing {Mo2O7} building block: hydrothermal synthesis and structural characterization of CoMo2O7(4,4'-bipy)1.5".Journal of Coordination Chemistry 60.22-24(2007):2629-2636. |
入库方式: OAI收割
来源:福建物质结构研究所
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