Novel copper-complex-substituted tungstogermanates
文献类型：期刊论文
| 作者 | C. M. Wang ; S. T. Zheng ; G. Y. Yang |
| 刊名 | Inorganic Chemistry
 |
| 出版日期 | 2007-02 |
| 卷号 | 46期号:3页码:616-618 |
| 关键词 | transition-metal-complexes hydrothermal syntheses crystal-structures magnetism electrochemistry polyoxometalate polyoxoanions polyoxotungstate silicotungstate clusters |
| ISSN号 | 0020-1669 |
| 中文摘要 | Two copper-complex-substituted tungstogermanates [Cu-5(2,2'-bpy)(6)(H2O)][GeW8O31]center dot 9H(2)O, 1, and {[Cu-5(2,2'-bpy)(5)(H2O)][GeW9O34]}(2)center dot 7H(2)O, 2 (2,2'-bpy = 2,2'-bipyridyl), have been hydrothermally synthesized and structurally characterized. X-ray structural analyses show that 1 is a rare tetralacunary Keggin anion of [B-beta-GeW8O31](10-) substituted by copper complexes, while dimer 2 consists of two trilacunary [B-alpha-GeW9O34](10-) Keggin units bridged by copper complexes. Magnetic measurement for 2 shows the presence of antiferromagnetic interactions within the dinuclear Cu2+ cations. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6641]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | C. M. Wang,S. T. Zheng,G. Y. Yang. Novel copper-complex-substituted tungstogermanates[J]. Inorganic Chemistry,2007,46(3):616-618. |
| APA | C. M. Wang,S. T. Zheng,&G. Y. Yang.(2007).Novel copper-complex-substituted tungstogermanates.Inorganic Chemistry,46(3),616-618. |
| MLA | C. M. Wang,et al."Novel copper-complex-substituted tungstogermanates".Inorganic Chemistry 46.3(2007):616-618. |
入库方式： OAI收割
来源：福建物质结构研究所
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