Syntheses and structures of two novel salicylate-containing mononuclear manganese complexes
文献类型：期刊论文
| 作者 | H. S. Wang ; C. B. Ma ; M. Wang ; C. N. Chen ; Q. T. Liu |
| 刊名 | Chinese Journal of Structural Chemistry
 |
| 出版日期 | 2007 |
| 卷号 | 26期号:8页码:920-923 |
| 关键词 | Mn(II) salicylate crystal structure axially compressed octahedral geometry high-field epr high-frequency dinuclear mn(iii) |
| ISSN号 | 0254-5861 |
| 中文摘要 | Two salicylate containing mononuclear manganese complexes formulated as [Mn-(sal)(2)(CH3OH)(2)]center dot py (sal = salicylate, py = pyridine) 1 and (HNEt3)(2)[Mn(sal)(3)] 2 have been synthesized and characterized by elemental analysis, IR and single-crystal X-ray diffraction analyses. Crystal data for compound 1: monoclinic, space group C2/c, a = 30.748(6), b = 8.1933(13), c = 21.137(4) angstrom, beta = 126.772(4)degrees, V= 4265.5(13) angstrom(3), Z = 8, M-r = 471.34, D-c = 1.468 g/cm(3), mu = 0.667 mm(-1), F(000) = 1952, the final R = 0.0637, wR = 0.17 83 (I > 2 sigma(I)) and GOOF = 1.073; and those for compound 2: monoclinic, space group C2/c, a = 14.505(5), b = 11.048(4), c = 20.711(7) angstrom, beta = 103.603(6)degrees, V = 3225.6 (18) angstrom(3), Z 4, M-r = 668.65, D-c = 1.377 g/cm(3), mu = 0.466 mm(-1), F(000) = 1416, the final R = 0.0373, wR = 0. 1125 (I > 2 sigma(I)), and GOOF = 1.000. The Mn atoms of both complexes are six-coordinated in an axially elongated octahedral geometry for I and an axially compressed octahedral geometry for 2, and their oxidation states have been determined to be trivalent by bond valence sum calculation. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6656]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | H. S. Wang,C. B. Ma,M. Wang,et al. Syntheses and structures of two novel salicylate-containing mononuclear manganese complexes[J]. Chinese Journal of Structural Chemistry,2007,26(8):920-923. |
| APA | H. S. Wang,C. B. Ma,M. Wang,C. N. Chen,&Q. T. Liu.(2007).Syntheses and structures of two novel salicylate-containing mononuclear manganese complexes.Chinese Journal of Structural Chemistry,26(8),920-923. |
| MLA | H. S. Wang,et al."Syntheses and structures of two novel salicylate-containing mononuclear manganese complexes".Chinese Journal of Structural Chemistry 26.8(2007):920-923. |
入库方式： OAI收割
来源：福建物质结构研究所
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