Synthesis and structure of a manganese(II) complex: Mn-2 center dot(dinitrobenzoic acid)(4)center dot(1,10-phen)(2) (n)
文献类型：期刊论文
| 作者 | J. Wang ; M. H. Huang ; P. Liu ; W. D. Cheng ; L. M. Zhang |
| 刊名 | Chinese Journal of Structural Chemistry
 |
| 出版日期 | 2007 |
| 卷号 | 26期号:2页码:139-142 |
| ISSN号 | 0254-5861 |
| 关键词 | crystal structure manganese complex eight-membered ring one-dimensional chain biological relevance |
| 中文摘要 | The title compound, [Mn-2(.)(dinitrobenzoic acid)(4)(.)(1,10-phen)(2)](n), has a linear chain structure containing binuclear [Mn2(.)(dinitrobenzoic acid)4(1,10-phen)2] repeat units. It crystallizes in the triclinic system, space group P (1) over bar with a = 7.9261(8), b = 12.1329(15), c = 14.847(2) angstrom, alpha = 103.845(5), beta = 101.424(5), gamma = 92.618(4), M-r = 657.37, V = 1352.3(2) angstrom(3), Z = 2, D-c = 1.614 g/cm(3), F(000) = 666, mu = 0.567 min(-1), the final R = 0.0407 and wR = 0.1015 for 4081 observed reflections with I > 2 sigma(I). The Mn atom is six-coordinated by two N and four O atoms, forming a slightly distorted octahedral geometry. All Mn-O and Mn-N bond distances range from 2.093(2) to 2.310(2) angstrom. Two adjacent octahedral units are bridged together by two pairs of bi-monodentate carboxyl groups of different dinitrobenzoic acids to form an eight-membered ring with chair-typed configuration, thus generating a one-dimensional chain along the a axis. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6666]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | J. Wang,M. H. Huang,P. Liu,et al. Synthesis and structure of a manganese(II) complex: Mn-2 center dot(dinitrobenzoic acid)(4)center dot(1,10-phen)(2) (n)[J]. Chinese Journal of Structural Chemistry,2007,26(2):139-142. |
| APA | J. Wang,M. H. Huang,P. Liu,W. D. Cheng,&L. M. Zhang.(2007).Synthesis and structure of a manganese(II) complex: Mn-2 center dot(dinitrobenzoic acid)(4)center dot(1,10-phen)(2) (n).Chinese Journal of Structural Chemistry,26(2),139-142. |
| MLA | J. Wang,et al."Synthesis and structure of a manganese(II) complex: Mn-2 center dot(dinitrobenzoic acid)(4)center dot(1,10-phen)(2) (n)".Chinese Journal of Structural Chemistry 26.2(2007):139-142. |
入库方式： OAI收割
来源：福建物质结构研究所
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