A new Dawson-like polyoxotungstate {SbW18O60} encapsulating a pyramidal SbO3 group within a {W-18} cluster cage
文献类型：期刊论文
| 作者 | J. P. Wang ; P. T. Ma ; J. W. Zhao ; J. Y. Niu |
| 刊名 | Inorganic Chemistry Communications
 |
| 出版日期 | 2007-05 |
| 卷号 | 10期号:5页码:523-526 |
| 关键词 | hydrothermal synthesis polyoxometalates Dawson-like self-assembly crystal-structure anion heteropolyanion complexes chemistry |
| ISSN号 | 1387-7003 |
| 中文摘要 | A new organic-inorganic hybrid polyoxometalate based on Dawson-like polyoxotungstate cluster {SbW18O60}, formulated [Cu(2,2'-bPY)(3)](2)[Cu(2,2'-bpy)(2)Cl][Cu(2,2'-bpy)(2)]H-6[(SbW4W14O60)-W-v-O-vI] H2O (2,2'-bpy=2,2'-bipyridine) (1) has been synthesized hydro- 14 thermally and characterized by elemental analyses, IR, XPS, EPS, TG and X-ray single crystal diffraction. Structural analysis shows that the polyoxoanion consists of a Dawson-like polyoxotungstate cluster anion [(SbW4W14O60)-W-v-O-VI](13-) encapsulating a pyramidal SbO3 group dis- 1 4 tributing two central cavities of two {W9O33} entities with fractional occupancy (0.5) within the {W-18} cluster cage. (c) 2007 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6669]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | J. P. Wang,P. T. Ma,J. W. Zhao,et al. A new Dawson-like polyoxotungstate {SbW18O60} encapsulating a pyramidal SbO3 group within a {W-18} cluster cage[J]. Inorganic Chemistry Communications,2007,10(5):523-526. |
| APA | J. P. Wang,P. T. Ma,J. W. Zhao,&J. Y. Niu.(2007).A new Dawson-like polyoxotungstate {SbW18O60} encapsulating a pyramidal SbO3 group within a {W-18} cluster cage.Inorganic Chemistry Communications,10(5),523-526. |
| MLA | J. P. Wang,et al."A new Dawson-like polyoxotungstate {SbW18O60} encapsulating a pyramidal SbO3 group within a {W-18} cluster cage".Inorganic Chemistry Communications 10.5(2007):523-526. |
入库方式： OAI收割
来源：福建物质结构研究所
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