A convenient method for the conversion of Sn3S4 (2-) to Sn3S3(mu(3)-0H) (-): Syntheses, structures and characterizations of (Bu4N) Sn-3(mu(3)-OH)S-3(edt)(3) center dot DMF and (Bu4N) Sn-3(mu(3)-OH)S-3(edt)(3) center dot H2O (edt=1,2-ethanedithiolate)
文献类型：期刊论文
| 作者 | L. S. Wang ; T. L. Sheng ; J. J. Zhang ; S. M. Hu ; R. B. Fu ; X. T. Wu ; Y. M. Li ; X. H. Huang ; S. C. Xiang |
| 刊名 | Polyhedron
 |
| 出版日期 | 2007-03 |
| 卷号 | 26期号:5页码:1098-1104 |
| 关键词 | cluster tin sulfides oxy-sulfides hydrogen bond layered tin(iv) sulfide ion-exchange properties tin-sulfur crystal-structures clusters chemistry trinuclear networks ternary zn |
| ISSN号 | 0277-5387 |
| 中文摘要 | Two new trinuclear tin(IV) oxy-sulfide complexes, (Bu4N)[Sn-3(mu(3)-OH)S-3(edt)(3)]center dot DMF (1) and (Bu4N)[Sn-3(mu(3)-OH)S-3(edt)(3)]center dot H2O (2), which are the same salt with different solvates, were unexpectedly obtained by the reaction of (Bu4N)(2)[Sn3S4(edt)(3)] with CuCl2 (Or KCuI2) and Zn(phen)(SCN)(2) (or Cd(phen)(SCN)(2)), respectively. The two complexes have been characterized by X-ray single crystal diffraction, IR, far-IR, Raman, H-1 NMR, ES-MS and element analysis. X-ray structure determinations reveal that complexes 1 and 2 possess the same incomplete cubane-like anion cluster of [Sn-3(mu(3)-OH)S-3(edt)(3)](-) (c) 2006 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6670]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | L. S. Wang,T. L. Sheng,J. J. Zhang,et al. A convenient method for the conversion of Sn3S4 (2-) to Sn3S3(mu(3)-0H) (-): Syntheses, structures and characterizations of (Bu4N) Sn-3(mu(3)-OH)S-3(edt)(3) center dot DMF and (Bu4N) Sn-3(mu(3)-OH)S-3(edt)(3) center dot H2O (edt=1,2-ethanedithiolate)[J]. Polyhedron,2007,26(5):1098-1104. |
| APA | L. S. Wang.,T. L. Sheng.,J. J. Zhang.,S. M. Hu.,R. B. Fu.,...&S. C. Xiang.(2007).A convenient method for the conversion of Sn3S4 (2-) to Sn3S3(mu(3)-0H) (-): Syntheses, structures and characterizations of (Bu4N) Sn-3(mu(3)-OH)S-3(edt)(3) center dot DMF and (Bu4N) Sn-3(mu(3)-OH)S-3(edt)(3) center dot H2O (edt=1,2-ethanedithiolate).Polyhedron,26(5),1098-1104. |
| MLA | L. S. Wang,et al."A convenient method for the conversion of Sn3S4 (2-) to Sn3S3(mu(3)-0H) (-): Syntheses, structures and characterizations of (Bu4N) Sn-3(mu(3)-OH)S-3(edt)(3) center dot DMF and (Bu4N) Sn-3(mu(3)-OH)S-3(edt)(3) center dot H2O (edt=1,2-ethanedithiolate)".Polyhedron 26.5(2007):1098-1104. |
入库方式： OAI收割
来源：福建物质结构研究所
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