Synthesis, crystal structure and spectral properties of Fe-3(2,2'-bipy)(6)(ox)(3) center dot 12.25H(2)O complex
文献类型:期刊论文
作者 | X. Wang ; Y. H. Xu ; X. Y. Song ; L. Li ; D. Z. Liao ; Z. H. Jiang ; S. P. Yan |
刊名 | Journal of Chemical Crystallography
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出版日期 | 2007-10 |
卷号 | 37期号:10页码:651-654 |
关键词 | crystal structure 2 iron(II) complex 2'-bipy hydrogen bonding dinuclear copper(ii) complexes magnetic-properties oxalato ligand |
ISSN号 | 1074-1542 |
中文摘要 | A novel iron (II) complex of formula [Fe-3(2,2'-bipy)(6)(ox)(3)]center dot 12.25H(2)O (2,2'-bipy = 2,2'-bipyridine, ox = oxalate) has been prepared and structurally characterized by X-ray crystallography. In the complex, the metal atoms are six-coordinated in distorted octahedral environment. In the complex [Fe(ox)(3)](4-) anions and water molecules are linked together into 1D chain structure by hydrogen interaction. The red crystal of the complex is monoclinic, space group P2(1)/c, with a = 22.932(6) angstrom, b = 13.715(4) angstrom, c = 22.493(6) angstrom, beta = 93.177(5)degrees, and V = 7063(3) angstrom(3) with Z = 4. |
语种 | 英语 |
公开日期 | 2013-04-01 |
源URL | [http://ir.fjirsm.ac.cn/handle/350002/6700] ![]() |
专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
推荐引用方式 GB/T 7714 | X. Wang,Y. H. Xu,X. Y. Song,et al. Synthesis, crystal structure and spectral properties of Fe-3(2,2'-bipy)(6)(ox)(3) center dot 12.25H(2)O complex[J]. Journal of Chemical Crystallography,2007,37(10):651-654. |
APA | X. Wang.,Y. H. Xu.,X. Y. Song.,L. Li.,D. Z. Liao.,...&S. P. Yan.(2007).Synthesis, crystal structure and spectral properties of Fe-3(2,2'-bipy)(6)(ox)(3) center dot 12.25H(2)O complex.Journal of Chemical Crystallography,37(10),651-654. |
MLA | X. Wang,et al."Synthesis, crystal structure and spectral properties of Fe-3(2,2'-bipy)(6)(ox)(3) center dot 12.25H(2)O complex".Journal of Chemical Crystallography 37.10(2007):651-654. |
入库方式: OAI收割
来源:福建物质结构研究所
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