catena-Poly pentaaquathulium(III) -mu-5-sulfonatobenzene-1,3-dicarboxyl ato 4,4'-bipyridyl 1.5-solvate hemihydrate
文献类型：期刊论文
| 作者 | Y. L. Wang ; Q. Y. Liu ; L. Xu |
| 刊名 | Acta Crystallographica Section C-Crystal Structure Communications
 |
| 出版日期 | 2007-07 |
| 卷号 | 63页码:M304-M307 |
| 关键词 | acid monosodium salt 4 crystal-structures 4'-bipyridine pi interactions network framework binding chain |
| ISSN号 | 0108-2701 |
| 中文摘要 | The crystal structure of the title compound, {[Tm(C8H3O7S)-( H2O)(5)]center dot 1.5C(10)H(8)N(2)center dot 0.5H(2)O}(n), is built up from two [Tm-( SIP)(H2O)(5)] molecules (SIP3 is 5-sulfonatobenzene-1,3-dicarboxylate), three 4,4'-bipyridyl (bpy) molecules and one solvent water molecule. One of the bpy molecules and the solvent water molecule are located on an inversion centre and a twofold rotation axis, respectively. The Tm III ion coordination is composed of four carboxylate O atoms from two trianionic SIP3- ligands and five coordinated water molecules. The Tm3+ ions are linked by the SIP3- ligands to form a one-dimensional zigzag chain propagating along the c axis. The chains are linked by interchain O-H center dot center dot center dot O hydrogen bonds to generate a two-dimensional layered structure. The bpy molecules are not involved in coordination but are linked by O-H center dot center dot center dot N hydrogen bonds to form two-dimensional layers. The two-dimensional layers are further bridged by the bpy molecules as pillars and the solvent water molecules through hydrogen bonds, giving a three-dimensional supramolecular structure. pi-pi stacking interactions between the parallel aromatic rings, arranged in an offset fashion with a face-to-face distance of 3.566 (1) angstrom, are observed in the crystal packing. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6713]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | Y. L. Wang,Q. Y. Liu,L. Xu. catena-Poly pentaaquathulium(III) -mu-5-sulfonatobenzene-1,3-dicarboxyl ato 4,4'-bipyridyl 1.5-solvate hemihydrate[J]. Acta Crystallographica Section C-Crystal Structure Communications,2007,63:M304-M307. |
| APA | Y. L. Wang,Q. Y. Liu,&L. Xu.(2007).catena-Poly pentaaquathulium(III) -mu-5-sulfonatobenzene-1,3-dicarboxyl ato 4,4'-bipyridyl 1.5-solvate hemihydrate.Acta Crystallographica Section C-Crystal Structure Communications,63,M304-M307. |
| MLA | Y. L. Wang,et al."catena-Poly pentaaquathulium(III) -mu-5-sulfonatobenzene-1,3-dicarboxyl ato 4,4'-bipyridyl 1.5-solvate hemihydrate".Acta Crystallographica Section C-Crystal Structure Communications 63(2007):M304-M307. |
入库方式： OAI收割
来源：福建物质结构研究所
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