Crystal structure of catena- (tetrakis-mu(2)-acetato-mu(2)-4,4 '-bipyridine) dicopper(II) acetonitrile solvate
文献类型:期刊论文
作者 | Y. H. Wen ; Y. H. He ; Y. L. Feng ; S. W. Ng |
刊名 | Chinese Journal of Structural Chemistry
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出版日期 | 2007 |
卷号 | 26期号:1页码:29-32 |
关键词 | Cu complex paddle-wheel unit crystal structure guest molecule polymer |
ISSN号 | 0254-5861 |
中文摘要 | The title compound, [Cu-2(CH3COO)(4)(C8H10N2)](n)center dot nCH(3)CN 1 (C8H10N2, 4,4'-bipy 4,4'-bipyridine), has been solvothermally synthesized in CH3CN and characterized by X-ray diffraction. The crystal is of monoclinic, space group Cc with a = 22.626(6), b = 14.012(4), c 15.106(4) angstrom, beta = 107.610(3)degrees, V = 4565(2) angstrom(3), C20H23Cu2N3O8, M-r = 560.49, Z = 8, D-c = 1.631 g/cm(3), mu = 1.914 mm(-1), Flack parameter = 0.48(1), F(000) = 2288, R = 0.042 and wR = 0.098 for 8887 observed reflections (I > 2 sigma(I)). It consists of nearly linear one-dimensional chains [Cu-2(CH3COO)(4)(C8H10N2)](n) derived from paddle-wheel [Cu-2(CH3COO)(4)] unit linked by 4,4'-bipy, and CH3CN as guest molecule regularly decorates between the chains. |
语种 | 英语 |
公开日期 | 2013-04-01 |
源URL | [http://ir.fjirsm.ac.cn/handle/350002/6735] ![]() |
专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
推荐引用方式 GB/T 7714 | Y. H. Wen,Y. H. He,Y. L. Feng,et al. Crystal structure of catena- (tetrakis-mu(2)-acetato-mu(2)-4,4 '-bipyridine) dicopper(II) acetonitrile solvate[J]. Chinese Journal of Structural Chemistry,2007,26(1):29-32. |
APA | Y. H. Wen,Y. H. He,Y. L. Feng,&S. W. Ng.(2007).Crystal structure of catena- (tetrakis-mu(2)-acetato-mu(2)-4,4 '-bipyridine) dicopper(II) acetonitrile solvate.Chinese Journal of Structural Chemistry,26(1),29-32. |
MLA | Y. H. Wen,et al."Crystal structure of catena- (tetrakis-mu(2)-acetato-mu(2)-4,4 '-bipyridine) dicopper(II) acetonitrile solvate".Chinese Journal of Structural Chemistry 26.1(2007):29-32. |
入库方式: OAI收割
来源:福建物质结构研究所
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