Linear oxalato- and 4,4 '-dipyridyldisulfide-bridged copper(II) coordination polymer involving in situ ligand synthesis
文献类型:期刊论文
作者 | B. L. Wu ; Y. Q. Xu ; Y. Q. Gong ; Y. G. Huang ; M. C. Hong |
刊名 | Journal of Coordination Chemistry
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出版日期 | 2007 |
卷号 | 60期号:22-24页码:2527-2532 |
关键词 | copper(II) complex 4 situ ligand synthesis 4'-dipyridyl disulfide single crystal structure cu-ii complexes m(hfac)(2) isomerism anions mn |
ISSN号 | 0095-8972 |
中文摘要 | The reaction of 1,3-bis(pyridyl-4-ylthio)propan-2-one with Cu(ClO4)(2)center dot 6H(2)O gave a new complex [Cu-2(4PDS)(2)(ox)(H2O)(4)](ClO4)(2)](n) (4PDS=4,4'-dipyridyldisulfide ox=oxalate), with 4PDS and ox being created by the Cu(II)-assisted oxidation of 1,3-bis(pyridyl-4-ylthio)propan-2-one. The complex determined by X-ray crystallography is a I D polymer, in which metallacycles formed by two 4PDS and two Cu(II) ions are further bridged through ox anions. It crystallizes in the orthorhombic system, space group Fddd with lattice parameters a = 15.106(2), b = 23.667(4), c = 27.637(3)angstrom and Z = 8. |
语种 | 英语 |
公开日期 | 2013-04-01 |
源URL | [http://ir.fjirsm.ac.cn/handle/350002/6736] ![]() |
专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
推荐引用方式 GB/T 7714 | B. L. Wu,Y. Q. Xu,Y. Q. Gong,et al. Linear oxalato- and 4,4 '-dipyridyldisulfide-bridged copper(II) coordination polymer involving in situ ligand synthesis[J]. Journal of Coordination Chemistry,2007,60(22-24):2527-2532. |
APA | B. L. Wu,Y. Q. Xu,Y. Q. Gong,Y. G. Huang,&M. C. Hong.(2007).Linear oxalato- and 4,4 '-dipyridyldisulfide-bridged copper(II) coordination polymer involving in situ ligand synthesis.Journal of Coordination Chemistry,60(22-24),2527-2532. |
MLA | B. L. Wu,et al."Linear oxalato- and 4,4 '-dipyridyldisulfide-bridged copper(II) coordination polymer involving in situ ligand synthesis".Journal of Coordination Chemistry 60.22-24(2007):2527-2532. |
入库方式: OAI收割
来源:福建物质结构研究所
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