Homochiral metal-organic coordination networks from L-typtophan
文献类型：期刊论文
| 作者 | Y. Xie ; Y. Yan ; H. H. Wu ; G. P. Yong ; Y. Cui ; Z. Y. Wang ; L. Pan ; J. Li ; R. Fan ; R. P. Li ; Y. C. Tian ; G. Q. Pan ; L. S. Sheng ; X. Li |
| 刊名 | Inorganica Chimica Acta
 |
| 出版日期 | 2007-04 |
| 卷号 | 360期号:5页码:1669-1677 |
| 关键词 | natural L-typtophan coordination networks helical chain 2D networks homochiral building unit chiral revulsive nonlinear-optical properties asymmetric catalysis crystal structure building-blocks ternary complex x-ray framework polymers design solids |
| ISSN号 | 0020-1693 |
| 中文摘要 | Three homochiral metal-organic coordination networks [Co(2)(L-Trp)(2)(Py)(6)].Py . (ClO(4))(2) (1), [Ni(L-Trp)(Py)(3)] . H(2)O . ClO(4) (2) and [Co(2)(L-Trp)(INT)(2)(H(2)O)(2)(ClO(4))] (3), all containing natural amino acid L-HTrp (L-typtophan), were hydrothermally synthesized and structurally characterized. The compounds I and 2 crystallize in the orthorhombic space group C222(t), with a = 10.731(2) angstrom, b = 19.709(4) angstrom, c = 27.365(6) angstrom and Z = 4 for 1 and a = 10.710(10) angstrom, b = 20.088(18) angstrom, c = 27.63(3) angstrom and Z = 8 for 2, respectively. The compound 3 has the monoclinic space group P2(1), with a = 8.1934(14) angstrom, b = 13.209(2) angstrom, c = 12.464(2) angstrom, beta = 104.107(3)degrees and Z = 2. Both 1 and 2 consist of 1D helical chains. Compound 3 is composed of 2D networks, which further assemble into a 3D supramolecular structure via weak interlayer interactions. The optically pure amino acid L-HTrp plays an important role leading to homochiral structures reported here. (c) 2006 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6763]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | Y. Xie,Y. Yan,H. H. Wu,et al. Homochiral metal-organic coordination networks from L-typtophan[J]. Inorganica Chimica Acta,2007,360(5):1669-1677. |
| APA | Y. Xie.,Y. Yan.,H. H. Wu.,G. P. Yong.,Y. Cui.,...&X. Li.(2007).Homochiral metal-organic coordination networks from L-typtophan.Inorganica Chimica Acta,360(5),1669-1677. |
| MLA | Y. Xie,et al."Homochiral metal-organic coordination networks from L-typtophan".Inorganica Chimica Acta 360.5(2007):1669-1677. |
入库方式： OAI收割
来源：福建物质结构研究所
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