Luminescent Au3Ag6 heterononanuclear complex of 1-ethynylcyclopentanol
文献类型：期刊论文
| 作者 | Z. L. Xie ; Q. H. Wei ; L. Y. Zhang ; Z. N. Chen |
| 刊名 | Inorganic Chemistry Communications
 |
| 出版日期 | 2007-10 |
| 卷号 | 10期号:10页码:1206-1209 |
| 关键词 | alkynyl crystal structure gold luminescence silver d(10) metal-complexes silver(i) complexes alkynyl complexes coordination ag arylacetylides copper(i) moieties ligands ch3 |
| ISSN号 | 1387-7003 |
| 中文摘要 | Reaction of polymeric species (AgC CC5H8OH)(n)(HC CC5H8OH = 1-ethynylcyclopentanol) with binuclear precursor [Au-2(mu-dppm)(2)](PF6)(2) (dppm = bis(diphenylphospnino)methane) caused isolation of Au3Ag6 heterononanuclear complex [Au3Ag6(mu-dppm)(3)(mu(3)-eta(1)-C CC5H8OH)(6)](PF6)(3). The Au3Ag6 (mu(3)-C CC5H8OH)(6) skeleton exhibits a hexagonal prismatic structure formed by mu(3)-eta(1)-C CC5H8OH bound to the Au3Ag6 cluster core. The compound is luminescent in both solid state and dichloromethane at both 298 and 77 K with the room temperature lifetimes in microsecond ranges, suggesting an emissive triplet parentage. (c) 2007 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6764]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | Z. L. Xie,Q. H. Wei,L. Y. Zhang,et al. Luminescent Au3Ag6 heterononanuclear complex of 1-ethynylcyclopentanol[J]. Inorganic Chemistry Communications,2007,10(10):1206-1209. |
| APA | Z. L. Xie,Q. H. Wei,L. Y. Zhang,&Z. N. Chen.(2007).Luminescent Au3Ag6 heterononanuclear complex of 1-ethynylcyclopentanol.Inorganic Chemistry Communications,10(10),1206-1209. |
| MLA | Z. L. Xie,et al."Luminescent Au3Ag6 heterononanuclear complex of 1-ethynylcyclopentanol".Inorganic Chemistry Communications 10.10(2007):1206-1209. |
入库方式： OAI收割
来源：福建物质结构研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。