Syntheses, characterization and luminescence of Pt-M (M = Re, Ru, Gd) heteronuclear complexes with 5-ethynyl-2,2 '-bipyridine
文献类型：期刊论文
| 作者 | H. B. Xu ; L. Y. Zhang ; Z. N. Chen |
| 刊名 | Inorganica Chimica Acta
 |
| 出版日期 | 2007-01 |
| 卷号 | 360期号:1页码:163-169 |
| 关键词 | alkynyl 2 gadolinium 2'-bipyridine luminescence platinum P ligands rhenium ruthenium transition-metal-complexes structural characterization building-block construction platinum ruthenium(ii) ligands acetylides bipyridine |
| ISSN号 | 0020-1693 |
| 中文摘要 | Incorporation of diplatinum component [Pt-2(mu-dppm)(2)(C Cbpy)(4)] (1, dppm = Ph2PCH2PPh2, C Cbpy = 2,2'-dipyridyl-5-acetylide) with Re(CO)(5)Cl, Ru(bpy)(2)Cl-2 (bpy = 2,2'-bipyridine) and Gd(hfac)(3)(H2O)(2) (Hhfac = hexafluoroacetylacetone) via 2,2'-dipyridyl chelating induced isolation of (Pt2Ru4II)-Ru-II (2), (Pt2Ru4II)-Ru-II (3), and (Pt2Gd2III)-Gd-II (4) complexes, respectively. The structures of 2 and 4 were determined by X-ray single crystal diffraction. Intense low-energy absorptions occur in the range 360-510 nm originating from metal-to-ligand charge transfer (MLCT) transitions. These compounds display photoluminescence in both solid states and dichloromethane at room temperature with emissive lifetimes in the range of microseconds. (c) 2006 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6773]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | H. B. Xu,L. Y. Zhang,Z. N. Chen. Syntheses, characterization and luminescence of Pt-M (M = Re, Ru, Gd) heteronuclear complexes with 5-ethynyl-2,2 '-bipyridine[J]. Inorganica Chimica Acta,2007,360(1):163-169. |
| APA | H. B. Xu,L. Y. Zhang,&Z. N. Chen.(2007).Syntheses, characterization and luminescence of Pt-M (M = Re, Ru, Gd) heteronuclear complexes with 5-ethynyl-2,2 '-bipyridine.Inorganica Chimica Acta,360(1),163-169. |
| MLA | H. B. Xu,et al."Syntheses, characterization and luminescence of Pt-M (M = Re, Ru, Gd) heteronuclear complexes with 5-ethynyl-2,2 '-bipyridine".Inorganica Chimica Acta 360.1(2007):163-169. |
入库方式： OAI收割
来源：福建物质结构研究所
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