Synthesis and amino acids complexation properities of thiacalix 4 -1,3-2,4-aza-bis-crowns
文献类型：期刊论文
| 作者 | F. F. Yang ; C. Y. Huang ; X. Zhao ; S. N. Zheng ; Q. Peng |
| 刊名 | Chemical Journal of Chinese Universities-Chinese
 |
| 出版日期 | 2007-05 |
| 卷号 | 28期号:5页码:885-888 |
| 关键词 | thiacalix[4]biscrown aza amino acid complexation cation extraction ability unprecedented cyclizations mitsunobu protocol anion recognition ethers |
| ISSN号 | 0251-0790 |
| 中文摘要 | Thiacalix [4] arene is an interesting novel member of the calixarene family. Thlacalix [4] crowns were paid much attention due to their particular structures and excellent complexation capabilities. In this paper, by reacting p-tert-butylthiacalix [4] arene tetrahydrazide derivative 2 with o-phthadaldehyde, the first example of thiacalix[4]-1,3-2,4-aza-bis-crowns with 1,3-alternate conformation was prepared with "1 + 2" condensation mode in a 65% yield. Its structure was characterized by elemental analysis, ESI-MS, H-1 NMR spectrum. Its complexation properties for series of a-amino acids were studied via UV-Vis and H-1 NMR spectra. Their high complexing constants suggest novel thiacalix [4] biscrown 3 possessed excellent complexation abilities for tested amino acids. the correlation coefficients and the H-1 NMR spectra change of complexation experiments indicate that compound 3 formed 1:1 stoichiometric complex with amino acids. |
| 语种 | 中文 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6801]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | F. F. Yang,C. Y. Huang,X. Zhao,et al. Synthesis and amino acids complexation properities of thiacalix 4 -1,3-2,4-aza-bis-crowns[J]. Chemical Journal of Chinese Universities-Chinese,2007,28(5):885-888. |
| APA | F. F. Yang,C. Y. Huang,X. Zhao,S. N. Zheng,&Q. Peng.(2007).Synthesis and amino acids complexation properities of thiacalix 4 -1,3-2,4-aza-bis-crowns.Chemical Journal of Chinese Universities-Chinese,28(5),885-888. |
| MLA | F. F. Yang,et al."Synthesis and amino acids complexation properities of thiacalix 4 -1,3-2,4-aza-bis-crowns".Chemical Journal of Chinese Universities-Chinese 28.5(2007):885-888. |
入库方式： OAI收割
来源：福建物质结构研究所
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