Syntheses, crystal structures and photoluminescence of three coordination polymers with 2,3-pyrazinedicarboxylic acid and N-donor ligands
文献类型:期刊论文
作者 | H. Yin ; S. X. Liu |
刊名 | Polyhedron
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出版日期 | 2007-08 |
卷号 | 26期号:13页码:3103-3111 |
关键词 | supermolecular chemistry pyrazine-2 cadmium 3-dicarboxylate copper pyrazinedicarboxylic acid mixed ligands magnetic-properties chain silver(i) manganese(ii) cadmium(ii) adsorption complexes molecules solids |
ISSN号 | 0277-5387 |
中文摘要 | The reactions between Cd(OAC)(2)/Cu(NO3)(2) and mixed ligands (2,3-pyrazinedicarboxylic acid (pzdc) and N-donor ligands) under different reaction conditions give the three title complexes 1, 2 and 3. There is a (4,8) net 2D network structure and a rectangular grid network structure in the cadmium complexes [Cd(pzdc)(phen)] center dot H2O (1) and Cd-2(pzdC)(2)(4,4'-bpy)(H2O)(2) (2), respectively. The complex [CU4(pzdC)(4)(phen)2(H'0)(4)] - I OH,O (3) has a I D zigzag chain structure. The influences of coordination modes of the pzdc ligand and N-donor ligands on the superstructural diversity have been discussed. Complexes 1 and 2 exhibit strong fluorescent emission bands in the solid state at room temperature. The EPR spectrum of 3 is typical for a square-pyramidal geometry of copper (II) ions. (c) 2007 Elsevier Ltd. All rights reserved. |
语种 | 英语 |
公开日期 | 2013-04-01 |
源URL | [http://ir.fjirsm.ac.cn/handle/350002/6824] ![]() |
专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
推荐引用方式 GB/T 7714 | H. Yin,S. X. Liu. Syntheses, crystal structures and photoluminescence of three coordination polymers with 2,3-pyrazinedicarboxylic acid and N-donor ligands[J]. Polyhedron,2007,26(13):3103-3111. |
APA | H. Yin,&S. X. Liu.(2007).Syntheses, crystal structures and photoluminescence of three coordination polymers with 2,3-pyrazinedicarboxylic acid and N-donor ligands.Polyhedron,26(13),3103-3111. |
MLA | H. Yin,et al."Syntheses, crystal structures and photoluminescence of three coordination polymers with 2,3-pyrazinedicarboxylic acid and N-donor ligands".Polyhedron 26.13(2007):3103-3111. |
入库方式: OAI收割
来源:福建物质结构研究所
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