Hydrothermal synthesis and characterization of nanometer Ce1-xCoxO2-delta solid solutions
文献类型：期刊论文
| 作者 | G. F. Zhang ; Y. F. Xue ; J. X. Xu ; X. Q. Qiu ; G. S. Li ; L. P. Li |
| 刊名 | Chemical Journal of Chinese Universities-Chinese
 |
| 出版日期 | 2007-04 |
| 卷号 | 28期号:4页码:603-607 |
| 关键词 | hydrothermal synthesis cobalt doping oxygen vacancy solubility ceria catalysts pressure powders oxides co |
| ISSN号 | 0251-0790 |
| 中文摘要 | Using (NH4)(2)S2O8 and NH4OH as the oxidizer and chelating agent, respectively, Ce1-xCoxO2-delta solid solutions were synthesized under hydrothermal conditions and the optimum preparation parameters were explored. The obtained solid solutions had a cubic fluorite structure, and the average particle size was about 4 nm. The lattice parameter monotonously decreased with increasing the cobalt content. The solubility of x = 0.06 was determined by combining XRD and Raman techniques. Cobalt ions are found to be in a mixed valence state of Co2+/Co3+ in CeO2 lattice. Increasing the cobalt content resulted in a clear blue shift of the absorption threshold edge and an increase of bulk conductivity. |
| 语种 | 中文 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6864]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | G. F. Zhang,Y. F. Xue,J. X. Xu,et al. Hydrothermal synthesis and characterization of nanometer Ce1-xCoxO2-delta solid solutions[J]. Chemical Journal of Chinese Universities-Chinese,2007,28(4):603-607. |
| APA | G. F. Zhang,Y. F. Xue,J. X. Xu,X. Q. Qiu,G. S. Li,&L. P. Li.(2007).Hydrothermal synthesis and characterization of nanometer Ce1-xCoxO2-delta solid solutions.Chemical Journal of Chinese Universities-Chinese,28(4),603-607. |
| MLA | G. F. Zhang,et al."Hydrothermal synthesis and characterization of nanometer Ce1-xCoxO2-delta solid solutions".Chemical Journal of Chinese Universities-Chinese 28.4(2007):603-607. |
入库方式： OAI收割
来源：福建物质结构研究所
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