Solvothermal synthesis, crystal structure, and thermal stability of three-layered thioantimonate(III) complexes: Ni(C3H10N2)(3) Sb4S7, C4H14N2 Sb8S13 center dot H2O, and C6H18N2 Sb10S16 center dot H2O
文献类型：期刊论文
| 作者 | M. Zhang ; T. L. Sheng ; X. H. Huang ; R. B. Fu ; X. Wang ; S. M. Hu ; S. C. Xiang ; X. T. Wu |
| 刊名 | European Journal of Inorganic Chemistry
 |
| 出版日期 | 2007-04 |
| 期号 | 11页码:1606-1612 |
| 关键词 | thioantimonates solvothermal synthesis cations layered compounds structure-directing agents hydrothermal synthesis layered thioantimonate(iii) antimony-sulfide metal-complexes transition chain la compound ligands |
| ISSN号 | 1434-1948 |
| 中文摘要 | Three new thioantimonate(III) complexes [Ni(1,2-PDA)(3)]-Sb4S7 (1) (1,2-PDA = 1,2-propanediamine), [dmenH(2)(2+)]-Sb8S13 center dot H2O (2) (dmen = N,N-dimethylethylenediamine), and [deenH(2)(2+)] Sb10S16 center dot H2O (3) (deen = N,N-diethylethylenediamine), prepared under solvothermal conditions, have been characterized by single-crystal X-ray diffraction, elemental analysis, and DTA-TG measurements. In compound 1, a rectangle-like Sb16S16 heteroring whose dimensions are about 8.1 X 14.7 angstrom is observed, this is the largest reported,pore in layered thioantimonates to date. Further condensation of the Sb16S16 heterorings resulted in an unprecedented framework of the five-atom thick SbxSyn- layer. In 2, a new member of SbnSn (n = 2, 3, 4, 8, 16, 30, 31, 32) heterocycles Sb15S15 heteroring has been obtained as the first example. In compound 3, the most particular feature is that when the secondary Sb-S bonds are considered the Sb2 atom becomes sevenfold coordinated. (c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6878]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | M. Zhang,T. L. Sheng,X. H. Huang,et al. Solvothermal synthesis, crystal structure, and thermal stability of three-layered thioantimonate(III) complexes: Ni(C3H10N2)(3) Sb4S7, C4H14N2 Sb8S13 center dot H2O, and C6H18N2 Sb10S16 center dot H2O[J]. European Journal of Inorganic Chemistry,2007(11):1606-1612. |
| APA | M. Zhang.,T. L. Sheng.,X. H. Huang.,R. B. Fu.,X. Wang.,...&X. T. Wu.(2007).Solvothermal synthesis, crystal structure, and thermal stability of three-layered thioantimonate(III) complexes: Ni(C3H10N2)(3) Sb4S7, C4H14N2 Sb8S13 center dot H2O, and C6H18N2 Sb10S16 center dot H2O.European Journal of Inorganic Chemistry(11),1606-1612. |
| MLA | M. Zhang,et al."Solvothermal synthesis, crystal structure, and thermal stability of three-layered thioantimonate(III) complexes: Ni(C3H10N2)(3) Sb4S7, C4H14N2 Sb8S13 center dot H2O, and C6H18N2 Sb10S16 center dot H2O".European Journal of Inorganic Chemistry .11(2007):1606-1612. |
入库方式： OAI收割
来源：福建物质结构研究所
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