中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Solvothermal synthesis, crystal structure, and thermal stability of three-layered thioantimonate(III) complexes: Ni(C3H10N2)(3) Sb4S7, C4H14N2 Sb8S13 center dot H2O, and C6H18N2 Sb10S16 center dot H2O

文献类型:期刊论文

作者M. Zhang ; T. L. Sheng ; X. H. Huang ; R. B. Fu ; X. Wang ; S. M. Hu ; S. C. Xiang ; X. T. Wu
刊名European Journal of Inorganic Chemistry
出版日期2007-04
期号11页码:1606-1612
关键词thioantimonates solvothermal synthesis cations layered compounds structure-directing agents hydrothermal synthesis layered thioantimonate(iii) antimony-sulfide metal-complexes transition chain la compound ligands
ISSN号1434-1948
中文摘要Three new thioantimonate(III) complexes [Ni(1,2-PDA)(3)]-Sb4S7 (1) (1,2-PDA = 1,2-propanediamine), [dmenH(2)(2+)]-Sb8S13 center dot H2O (2) (dmen = N,N-dimethylethylenediamine), and [deenH(2)(2+)] Sb10S16 center dot H2O (3) (deen = N,N-diethylethylenediamine), prepared under solvothermal conditions, have been characterized by single-crystal X-ray diffraction, elemental analysis, and DTA-TG measurements. In compound 1, a rectangle-like Sb16S16 heteroring whose dimensions are about 8.1 X 14.7 angstrom is observed, this is the largest reported,pore in layered thioantimonates to date. Further condensation of the Sb16S16 heterorings resulted in an unprecedented framework of the five-atom thick SbxSyn- layer. In 2, a new member of SbnSn (n = 2, 3, 4, 8, 16, 30, 31, 32) heterocycles Sb15S15 heteroring has been obtained as the first example. In compound 3, the most particular feature is that when the secondary Sb-S bonds are considered the Sb2 atom becomes sevenfold coordinated. (c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007.
语种英语
公开日期2013-04-01
源URL[http://ir.fjirsm.ac.cn/handle/350002/6878]  
专题福建物质结构研究所_中科院福建物质结构研究所_期刊论文
推荐引用方式
GB/T 7714
M. Zhang,T. L. Sheng,X. H. Huang,et al. Solvothermal synthesis, crystal structure, and thermal stability of three-layered thioantimonate(III) complexes: Ni(C3H10N2)(3) Sb4S7, C4H14N2 Sb8S13 center dot H2O, and C6H18N2 Sb10S16 center dot H2O[J]. European Journal of Inorganic Chemistry,2007(11):1606-1612.
APA M. Zhang.,T. L. Sheng.,X. H. Huang.,R. B. Fu.,X. Wang.,...&X. T. Wu.(2007).Solvothermal synthesis, crystal structure, and thermal stability of three-layered thioantimonate(III) complexes: Ni(C3H10N2)(3) Sb4S7, C4H14N2 Sb8S13 center dot H2O, and C6H18N2 Sb10S16 center dot H2O.European Journal of Inorganic Chemistry(11),1606-1612.
MLA M. Zhang,et al."Solvothermal synthesis, crystal structure, and thermal stability of three-layered thioantimonate(III) complexes: Ni(C3H10N2)(3) Sb4S7, C4H14N2 Sb8S13 center dot H2O, and C6H18N2 Sb10S16 center dot H2O".European Journal of Inorganic Chemistry .11(2007):1606-1612.

入库方式: OAI收割

来源:福建物质结构研究所

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