Synthesis and structure of (NH4)(4) (DMF)(2)Mo8O26 center dot 2CH(3)CH(2)OH center dot 2H(2)O (DMF=N,N-dimethylformamide)
文献类型：期刊论文
| 作者 | Q. Z. Zhang ; G. Q. Shao ; G. Chen ; H. Shen ; G. H. Lu ; R. Ping ; P. F. Xie ; Y. Jiang ; J. Zhang |
| 刊名 | Journal of Chemical Crystallography
 |
| 出版日期 | 2007-05 |
| 卷号 | 37期号:5页码:369-373 |
| 关键词 | octamolybdate anion DMF crystal structure crystal-structure octamolybdate chemistry solids |
| ISSN号 | 1074-1542 |
| 中文摘要 | A new organic-inorganic hybrid gamma-octamolybdate complex, (NH4)(4)[(C3H7NO)(2)Mo8O26]center dot 2CH(3)CH(2)OH center dot 2H(2)O was synthesized from the mixture of ethanol, DMF, 4-aminobenzoic acid, (NH4)(6)Mo7O24 center dot 4H(2)O, HCl and H2O. The structure was determined by X-ray crystallography. It crystallizes in monoclinic P2(1)/n space group with the crystal cell parameters of a = 8.8825(4), b = 21.1608(10), c = 11.1343(6) angstrom, beta = 104.7720(10)degrees, V = 2023.64(17) angstrom(3) and Z = 2. The crystal X-ray analysis shows that two DMF molecules are bound to gamma-octamolybdate anion. The molecular structure is stabilized by the complex hydrogen bonding. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6880]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | Q. Z. Zhang,G. Q. Shao,G. Chen,et al. Synthesis and structure of (NH4)(4) (DMF)(2)Mo8O26 center dot 2CH(3)CH(2)OH center dot 2H(2)O (DMF=N,N-dimethylformamide)[J]. Journal of Chemical Crystallography,2007,37(5):369-373. |
| APA | Q. Z. Zhang.,G. Q. Shao.,G. Chen.,H. Shen.,G. H. Lu.,...&J. Zhang.(2007).Synthesis and structure of (NH4)(4) (DMF)(2)Mo8O26 center dot 2CH(3)CH(2)OH center dot 2H(2)O (DMF=N,N-dimethylformamide).Journal of Chemical Crystallography,37(5),369-373. |
| MLA | Q. Z. Zhang,et al."Synthesis and structure of (NH4)(4) (DMF)(2)Mo8O26 center dot 2CH(3)CH(2)OH center dot 2H(2)O (DMF=N,N-dimethylformamide)".Journal of Chemical Crystallography 37.5(2007):369-373. |
入库方式： OAI收割
来源：福建物质结构研究所
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