Self-assembly of two fluorescent supramolecular frameworks constructed from unsymmetrical benzene tricarboxylate and bipyridine
文献类型：期刊论文
| 作者 | S. Zhang ; Z. Wang ; H. H. Zhang ; Y. N. Cao ; Y. X. Sun ; Y. P. Chen ; C. C. Huang ; X. H. Yu |
| 刊名 | Inorganica Chimica Acta
 |
| 出版日期 | 2007-05 |
| 卷号 | 360期号:8页码:2704-2710 |
| 关键词 | silver copper(I) mixed ligands hydrogen bonds supramolecular framework metal coordination polymers ray crystal-structure pi-pi interactions hydrothermal synthesis structural-characterization magnetic-properties organic polymer mixed-ligands complexes network |
| ISSN号 | 0020-1693 |
| 中文摘要 | Two new supramolecular compounds, [Ag(4,4'-bipy)](n) [Ag(HBTC)(n) (1) and [Cu(H(2)BTC)2,2-bipy)] (2) (HBTC/H(2)BTC = 1,2,4-benzenetricarboxylate, 4,4'-bipy/2,2'-bipy = 4,4'/2,2'-bipyridine), have been synthesized and characterized by elemental analyses, IR spectra, ultraviolet-visible diffuse reflection integral spectra (UV-Vis DRIS), fluorescent spectra, thermogravimetric analysis and single crystal X-ray diffraction analysis. It is noteworthy that there were two kinds of one-dimensional stairs-chain including cationic [Ag(4,4'-bipy)(n) chain and anionic [Ag(HBTC)(n) chain in 1. Furthermore, a two-dimensional double layer supramolecular framework was constructed through coordination bonds, hydrogen bonds, pi-pi stacking interactions and Ag center dot center dot center dot O weak coordinative interactions. The one-dimensional supramolecular chain of 2 was built from combining mononuclear [Cu(H(2)BTC)(2,2'-bipy)] by inter- and intramolecular hydrogen bonding interactions. Additionally, the two complexes exhibit intense blue or olivine luminescence at room temperature. (c) 2007 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6883]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | S. Zhang,Z. Wang,H. H. Zhang,et al. Self-assembly of two fluorescent supramolecular frameworks constructed from unsymmetrical benzene tricarboxylate and bipyridine[J]. Inorganica Chimica Acta,2007,360(8):2704-2710. |
| APA | S. Zhang.,Z. Wang.,H. H. Zhang.,Y. N. Cao.,Y. X. Sun.,...&X. H. Yu.(2007).Self-assembly of two fluorescent supramolecular frameworks constructed from unsymmetrical benzene tricarboxylate and bipyridine.Inorganica Chimica Acta,360(8),2704-2710. |
| MLA | S. Zhang,et al."Self-assembly of two fluorescent supramolecular frameworks constructed from unsymmetrical benzene tricarboxylate and bipyridine".Inorganica Chimica Acta 360.8(2007):2704-2710. |
入库方式： OAI收割
来源：福建物质结构研究所
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