Synthesis, structure, and properties of the first trimetallic phosphate Ni(H2O)(4) Cd(VO)(PO4)(2) with neutral 3-D pillared-layer framework
文献类型：期刊论文
| 作者 | S. F. Zhang ; G. Z. Liu ; S. T. Zheng ; G. Y. Yang |
| 刊名 | Journal of Solid State Chemistry
 |
| 出版日期 | 2007-06 |
| 卷号 | 180期号:6页码:1943-1948 |
| 关键词 | trimetallic phosphate hydrothermal synthesis crystal structure open framework state coordination chemistry hydrothermal synthesis vanadium phosphate crystal-structures tunnel structure oxovanadium phosphates hybrid materials cd(vo)2(po4)2 monophosphate subunits |
| ISSN号 | 0022-4596 |
| 中文摘要 | Hydrothermal reactions of VOSO4 center dot 3H(2)O, CdAc2 center dot 2H(2)O, NiCl2 center dot 6H(2)O, H3PO4, and H2O yield the first example of trimetallic phosphate materials, [Ni(H2O)(4)]Cd(VO)(PO4)(2) 1. The single-crystal X-ray diffraction shows that its structure consists of Cd/V/O binary metal oxide lamellas decorated by PO4 tetrahedra, which are further pillared by NiO2(H2O)4 octahedra to generate a neutral 3-D framework containing two intercrossing 8-MR channels where. the coordinated water molecules protrude into. Thermal and magnetic behaviors of this material were also measured. Crystal data: CdNiVP2O13H8, orthorhombic Ibca (No.73), a = 7.1307(2) angstrom, b = 18.6248(3) angstrom, c = 14.8046(2) angstrom, V = 1966.17(7) angstrom(3), Z = 8. (c) 2007 Elsevier Inc. All rights reserved. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6884]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | S. F. Zhang,G. Z. Liu,S. T. Zheng,et al. Synthesis, structure, and properties of the first trimetallic phosphate Ni(H2O)(4) Cd(VO)(PO4)(2) with neutral 3-D pillared-layer framework[J]. Journal of Solid State Chemistry,2007,180(6):1943-1948. |
| APA | S. F. Zhang,G. Z. Liu,S. T. Zheng,&G. Y. Yang.(2007).Synthesis, structure, and properties of the first trimetallic phosphate Ni(H2O)(4) Cd(VO)(PO4)(2) with neutral 3-D pillared-layer framework.Journal of Solid State Chemistry,180(6),1943-1948. |
| MLA | S. F. Zhang,et al."Synthesis, structure, and properties of the first trimetallic phosphate Ni(H2O)(4) Cd(VO)(PO4)(2) with neutral 3-D pillared-layer framework".Journal of Solid State Chemistry 180.6(2007):1943-1948. |
入库方式： OAI收割
来源：福建物质结构研究所
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