Combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions. 5. A novel tetrameric cluster of {(FeFe12III)-Fe-II(mu(3)-OH)(12)(mu(4)-PO4)(4)}(B-alpha-PW9O34)(4) (22- )
文献类型：期刊论文
| 作者 | J. W. Zhao ; J. Zhang ; S. T. Zheng ; G. Y. Yang |
| 刊名 | Inorganic Chemistry
 |
| 出版日期 | 2007-12 |
| 卷号 | 46期号:26页码:10944-10946 |
| ISSN号 | 0020-1669 |
| 关键词 | magnetic-properties crystal-structure complexes polyoxotungstate heteropolyanions tungstophosphate polyoxoanions coordination anions wheel |
| 中文摘要 | A novel tetrameric cluster, (en H-2)(3.5)H-15[{(FeFeIII)-Fe-II](12)(mu(3)-OH)(12)(mu(4)-PO4)(4)}(B-alpha-PW9O34)(4)]center dot 83H(2)O (1; en = ethylenediamine), has been hydrothermally synthesized and characterized by IR, optical diffuse reflectance, thermogravimetric analysis, and single-crystal X-ray diffraction. The skeleton of 1 is composed of four tri-Fe-III-substituted [Fe-3(III)(mu(3)-OH)(3)(B-alpha-PW9O34)](3-) Keggin moieties fused together through a (Fe2O2)-O-II unit and four mu(4)-PO4 bridges, resulting in a unique tetramer with C-2 symmetry. Magnetic measurements indicate that 1 reveals the antiferromagnetic interactions between Fe-II and Fe-III centers. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6911]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | J. W. Zhao,J. Zhang,S. T. Zheng,et al. Combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions. 5. A novel tetrameric cluster of {(FeFe12III)-Fe-II(mu(3)-OH)(12)(mu(4)-PO4)(4)}(B-alpha-PW9O34)(4) (22- )[J]. Inorganic Chemistry,2007,46(26):10944-10946. |
| APA | J. W. Zhao,J. Zhang,S. T. Zheng,&G. Y. Yang.(2007).Combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions. 5. A novel tetrameric cluster of {(FeFe12III)-Fe-II(mu(3)-OH)(12)(mu(4)-PO4)(4)}(B-alpha-PW9O34)(4) (22- ).Inorganic Chemistry,46(26),10944-10946. |
| MLA | J. W. Zhao,et al."Combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions. 5. A novel tetrameric cluster of {(FeFe12III)-Fe-II(mu(3)-OH)(12)(mu(4)-PO4)(4)}(B-alpha-PW9O34)(4) (22- )".Inorganic Chemistry 46.26(2007):10944-10946. |
入库方式： OAI收割
来源：福建物质结构研究所
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