Hydrothermal synthesis and structural characterization of three inorganic-organic composite sandwich-type phosphotungstates
文献类型：期刊论文
| 作者 | J. W. Zhao ; S. T. Zheng ; G. Y. Yang |
| 刊名 | Journal of Solid State Chemistry
 |
| 出版日期 | 2007-12 |
| 卷号 | 180期号:12页码:3317-3324 |
| 关键词 | polyoxometalates sandwich-type structure hydrothermal reaction trivacant Keggin derivatives trivacant heteropolytungstate derivatives x-ray structure transition-metal clusters m = co magnetic-properties organosilyl derivatives rational synthesis crystal-structure w-183 nmr keggin heteropolytungstates |
| ISSN号 | 0022-4596 |
| 中文摘要 | Three inorganic-organic composite sandwich-type phosphotungstates [Ni(tepa)(H2O)](4)H-2[Ni-4(H2O)(2)(alpha-B-PW9O34)(2)]center dot 8H(2)O (1), (enH(2))(3)[Ni-2(H2O)(10)][Ni-4(H2O)(2)(alpha-B-PW9O34)(2)]center dot en center dot 8H(2)O (2) and (enH(2))(10)[Mn-4(H2O)(2)(alpha-B-PW9O34)(2)](2)center dot 20H(2)O (3) (tepa = tetraethylenepentamine and en = ethylenediamine) have been synthesized by the hydrothermal reaction of the trivacant Keggin polyoxoanion [alpha-A-PW9O34](9-) with Ni2+ or Mn2+ ions in the presence of tepa or en and structurally characterized by IR spectra, elemental analysis, thermogravimetric analysis and variable temperature magnetic susceptibility. X-ray crystallographic analyses indicate that they all contain the classical tetra-M sandwiched polyoxoanions [M-4(H2O)(2)(alpha-B-PW9O34)(2)](10-) (M = Ni2+ or Mn2+) and nickelorganoamine cations or organoamine cations work as the charge balance ions. The tetra-M clusters in 1, 2 and 3 exhibit the familiar structural type of a beta-junction at the sites of metal incorporation. The study of magnetic property of 1 is indicative of a typical ferromagnetic coupling between Ni2+ cations. (C) 2007 Elsevier Inc. All rights reserved. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6913]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | J. W. Zhao,S. T. Zheng,G. Y. Yang. Hydrothermal synthesis and structural characterization of three inorganic-organic composite sandwich-type phosphotungstates[J]. Journal of Solid State Chemistry,2007,180(12):3317-3324. |
| APA | J. W. Zhao,S. T. Zheng,&G. Y. Yang.(2007).Hydrothermal synthesis and structural characterization of three inorganic-organic composite sandwich-type phosphotungstates.Journal of Solid State Chemistry,180(12),3317-3324. |
| MLA | J. W. Zhao,et al."Hydrothermal synthesis and structural characterization of three inorganic-organic composite sandwich-type phosphotungstates".Journal of Solid State Chemistry 180.12(2007):3317-3324. |
入库方式： OAI收割
来源：福建物质结构研究所
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