In situ ligand reactions under hydrothermal conditions afford a novel zinc-substituted polyoxovanadate dimer
文献类型：期刊论文
| 作者 | S. T. Zheng ; M. H. Wang ; G. Y. Yang |
| 刊名 | Inorganic Chemistry
 |
| 出版日期 | 2007-10 |
| 卷号 | 46期号:22页码:9503-9508 |
| 关键词 | magnetic-properties clusters complexes coordination chain polyoxotungstate polymer tungstophosphate frameworks molecules |
| ISSN号 | 0020-1669 |
| 中文摘要 | A novel polyoxovanadate (POV), [Zn(2,2(')-bPY)(3)](4)[(ppz){{Zn(tepa)}(2)ZnAs8V13O41(H2O)}(2)][As8V14O42(0.5H(2)O)](2)center dot 4H(2)O (1, 2,2(')-bpy = 2,2(')-bipyridine, ppz = piperazine, tepa = tetraethylenepentamine), has been hydrothermally synthesized and structurally characterized by elemental analysis, IR spectra, thermogravimetric analysis, magnetic measurement, and single-crystal X-ray diffraction analysis. Crystal data for 1: orthorhombic, Aba2, a = 28.3414(14) angstrom, b = 27.9995(16) angstrom, c = 41.5819(16) angstrom, V = 32997(3) angstrom(3), Z = 4, rho = 2.264 mg center dot cm(-3). X-ray structure analysis shows that the structure of 1 consists of one unique zinc-substituted POV dimer and two POV monomers. Interestingly, the formation of the zinc-substituted POV dimer involves two new in situ ligand reactions under hydrothermal conditions, the intermolecular and intramolecular deamination coupling reactions of dien. Magnetization measurement revealed the presence of antiferromagnetic interaction between V-IV ions in 1. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6916]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | S. T. Zheng,M. H. Wang,G. Y. Yang. In situ ligand reactions under hydrothermal conditions afford a novel zinc-substituted polyoxovanadate dimer[J]. Inorganic Chemistry,2007,46(22):9503-9508. |
| APA | S. T. Zheng,M. H. Wang,&G. Y. Yang.(2007).In situ ligand reactions under hydrothermal conditions afford a novel zinc-substituted polyoxovanadate dimer.Inorganic Chemistry,46(22),9503-9508. |
| MLA | S. T. Zheng,et al."In situ ligand reactions under hydrothermal conditions afford a novel zinc-substituted polyoxovanadate dimer".Inorganic Chemistry 46.22(2007):9503-9508. |
入库方式： OAI收割
来源：福建物质结构研究所
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