Extended Architectures constructed from sandwich tetra-metal-substituted polyoxotungstates and transition-metal complexes
文献类型：期刊论文
| 作者 | S. T. Zheng ; M. H. Wang ; G. Y. Yang |
| 刊名 | Chemistry-an Asian Journal
 |
| 出版日期 | 2007 |
| 卷号 | 2期号:11页码:1380-1387 |
| 关键词 | coordination polymers organic-inorganic hybrid composites polyoxometalates sandwich complexes tungsten coordinated water-molecules ray crystal-structures hydrothermal synthesis magnetic-properties polyoxometalate clusters chain fragments network polymer cu |
| ISSN号 | 1861-4728 |
| 中文摘要 | Three unprecedented 2D architectures made up of sandwich-type tetra-metal-substituted polyoxotung-states and transition-metal complexes, [Cu(dien)(H2O)](2){[Cu(dien)(H2O)](2)-[Cu(dien)(H2O)(2)](2)[Cu-4(SiW9O34)2]}. 5H(2)O (1; then = diethylenetriamine), [Zn(enMe)(2)(H2O)](2){[Zn(enMe)(2)](2)[Zn-4-(HenMe)(2)(PW9O34)(2)]}center dot 8H(2)O (2; enMe =1,2-diaminopropane), and [Zn(enMe)(2)-(H2O)](4)[Zn(enMe)(2)](2){(enMe)(2){[Zn-(enMe)(2)](2)[Zn-4(HSiW9O34)(2)]}{[Zn-(enMe)(2)(H2O)](2)[Zn-4(HSiW9O34)2]}}. 13H(2)O (3) were hydrothermally synthesized and structurally characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis, and single-crystal X-ray diffraction. Compound 1 consists of anions [Cu-4(SiW9O34)(2)](12-)linked by copper complexes into a 2D structure, whereas 2 is constructed from novel inorganic-organic hybrid anions [Zn-4(HenMe)(2)(PW9O34)(2)](8-)linked by zinc complexes into a 2D structure. The most interesting is the unique 2D network 3, which consists of anions [Zn-4(PW9O34)(2)](10-) with two types of bridging groups: zinc complexes and enMe ligands. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6919]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | S. T. Zheng,M. H. Wang,G. Y. Yang. Extended Architectures constructed from sandwich tetra-metal-substituted polyoxotungstates and transition-metal complexes[J]. Chemistry-an Asian Journal,2007,2(11):1380-1387. |
| APA | S. T. Zheng,M. H. Wang,&G. Y. Yang.(2007).Extended Architectures constructed from sandwich tetra-metal-substituted polyoxotungstates and transition-metal complexes.Chemistry-an Asian Journal,2(11),1380-1387. |
| MLA | S. T. Zheng,et al."Extended Architectures constructed from sandwich tetra-metal-substituted polyoxotungstates and transition-metal complexes".Chemistry-an Asian Journal 2.11(2007):1380-1387. |
入库方式： OAI收割
来源：福建物质结构研究所
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