Synthesis and structure of a 3D manganese coordination polymer with 1,3-bis(benzimidazol-1-ylmethyl)-2,4,6-trimethylbenzene and 1,5-naphthalenedisulfonate
文献类型：期刊论文
| 作者 | H. Zhou ; S. W. Du ; Z. H. Li |
| 刊名 | Chinese Journal of Structural Chemistry
 |
| 出版日期 | 2007 |
| 卷号 | 26期号:8页码:929-932 |
| 关键词 | solvothermal reaction bix=1 organic-inorganic polymer 4-bis(imidazol-1-ylmethyl)benzene 6-connected 3D net manganese complex architectures dinuclear benzene ligand |
| ISSN号 | 0254-5861 |
| 中文摘要 | The organic-inorganic hybrid polymer [Mn(mbbimb)(2)(1,5-nds)](n) 1 has been synthesized using 1,5-naphthalenedisulfonate (1,5-nds) and 1,3-bis(benzimidazol-1-ylmethyl)- 2,4, 6-trimethylbenzene (mbbimb) with Mn(OAC)(2)center dot 4H(2)O in solvothermal reaction. The X-ray crystal structure analysis indicates that 1 crystallizes in monoclinic, space group C2/c with a = 21.3546(17), b = 11.8841(7), c = 22.1588(16) angstrom, beta = 108.058(3)degrees, C60H54MnN8S2, M-r = 1102.17, Z=4,V = 5346.5(7) angstrom(3), D-c=1.369 g/cm(3), mu = 0.386 mm(-1), F(000) = 2300, S = 1.091, R = 0.0634 and wR = 0.1559 for 4641 observed reflections (I > 2 sigma(I)). The Mn center is six-coordinated to furnish a distorted octahedral geometry, and the. overall framework is a 6-connected 3D net. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6926]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | H. Zhou,S. W. Du,Z. H. Li. Synthesis and structure of a 3D manganese coordination polymer with 1,3-bis(benzimidazol-1-ylmethyl)-2,4,6-trimethylbenzene and 1,5-naphthalenedisulfonate[J]. Chinese Journal of Structural Chemistry,2007,26(8):929-932. |
| APA | H. Zhou,S. W. Du,&Z. H. Li.(2007).Synthesis and structure of a 3D manganese coordination polymer with 1,3-bis(benzimidazol-1-ylmethyl)-2,4,6-trimethylbenzene and 1,5-naphthalenedisulfonate.Chinese Journal of Structural Chemistry,26(8),929-932. |
| MLA | H. Zhou,et al."Synthesis and structure of a 3D manganese coordination polymer with 1,3-bis(benzimidazol-1-ylmethyl)-2,4,6-trimethylbenzene and 1,5-naphthalenedisulfonate".Chinese Journal of Structural Chemistry 26.8(2007):929-932. |
入库方式： OAI收割
来源：福建物质结构研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。