Synthesis, structure and second-order nonlinear optical activities of a new tungsten(O) compound with pyridine-2-thiolato ligand, Et4N W(pyS)(CO)(4) (pyS = C5H4NS-)
文献类型：期刊论文
| 作者 | Z. F. Zhou ; B. T. Zhuang ; Y. Q. Wei ; K. C. Wu ; Y. G. Yao |
| 刊名 | Chinese Journal of Structural Chemistry
 |
| 出版日期 | 2007 |
| 卷号 | 26期号:1页码:21-24 |
| 关键词 | tungsten(O)-compound synthesis structure nonlinear optical property cluster compounds crystal-structure complexes oxide |
| ISSN号 | 0254-5861 |
| 中文摘要 | The reaction of W(CO)(6) with pyOSNa (C5H4NOSNa) and Et4NCl in MeCN affords a new tungsten(0) complex [Et4N][W(pyS)(CO)(4)] 1 (M-r = 536.29). The crystal and molecular structures have been determined by X-ray single-crystal diffraction. Complex 1 crystallizes in the orthorhombic system, space group P2(1)2(1)2(1) with a = 8.2429(5), b = 9.1045(4), c = 26.8851(14) angstrom, beta = 90.00 degrees, V = 2017.66(18) angstrom(3), Z = 4, D-c = 1.765 g/cm(3), mu = 58.51 cm(-1), F(000) = 1048, the final R = 0.0204 and wR = 0.0400 for 4432 observed reflections with I > 2 sigma(I). X-ray structure analysis revealed that the molecule is acentric and has large first-order hyperpolarizability (7.2 x 10(-30) esu), so it could be an IR second-order nonlinear optical candidate material. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6932]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | Z. F. Zhou,B. T. Zhuang,Y. Q. Wei,et al. Synthesis, structure and second-order nonlinear optical activities of a new tungsten(O) compound with pyridine-2-thiolato ligand, Et4N W(pyS)(CO)(4) (pyS = C5H4NS-)[J]. Chinese Journal of Structural Chemistry,2007,26(1):21-24. |
| APA | Z. F. Zhou,B. T. Zhuang,Y. Q. Wei,K. C. Wu,&Y. G. Yao.(2007).Synthesis, structure and second-order nonlinear optical activities of a new tungsten(O) compound with pyridine-2-thiolato ligand, Et4N W(pyS)(CO)(4) (pyS = C5H4NS-).Chinese Journal of Structural Chemistry,26(1),21-24. |
| MLA | Z. F. Zhou,et al."Synthesis, structure and second-order nonlinear optical activities of a new tungsten(O) compound with pyridine-2-thiolato ligand, Et4N W(pyS)(CO)(4) (pyS = C5H4NS-)".Chinese Journal of Structural Chemistry 26.1(2007):21-24. |
入库方式： OAI收割
来源：福建物质结构研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。