Synthesis and photophysical properties of two kinds of substituted phthalocyaninatozinc
文献类型：期刊论文
| 作者 | X. L. Zhu ; X. Z. Xu ; L. Yang ; M. J. Lin ; J. D. Wang ; J. L. Huang |
| 刊名 | Spectroscopy and Spectral Analysis
 |
| 出版日期 | 2007-05 |
| 卷号 | 27期号:5页码:953-956 |
| 关键词 | phthalocyaninatozinc fluorescence spectra singlet oxygen photochemical properties complexes derivatives |
| ISSN号 | 1000-0593 |
| 中文摘要 | Two kinds of substituted phthalocyaninatozinc, tetra-beta-phthalimidobutoxy phthalocyaninatozinc (1) and tetra-beta-phthalimidomethyl phthalocyaninatozinc (2), were synthesized by mix melting method, which bear the same phthalimide substituents but the linking of the substituents to the phthalocyanine ring is different. The substituent linking to the phthalocyanine ring is one methylene in ZnPc (2), while the substituents linking to the phthalocyanine ring is four methylenes and one ather in ZnPc (1), in which ather is near by phthalocyanine ring. The absorption and fluorescence spectra and the abilities of singlet oxygen generation of these two phthalocyanines were compared with respect to the effect of different linked fashions. The magnitude of the redshift of absorption and fluorescence spectra relative to unsubstituded ZnPc is greater for tetra-beta-phthalimidobutoxy phthalocyaninatozinc: (1) than for tetra-p-phthalimidomethyl phthalocyaninatozinc (2). This result is related to the presence of stronger electron donating peripheral substituents of ZnPc (1), with Phi(F) of (1) is larger than that of (2) and the abilities of singlet oxygen generation of (1) is smaller than that of (2). |
| 语种 | 中文 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6955]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | X. L. Zhu,X. Z. Xu,L. Yang,et al. Synthesis and photophysical properties of two kinds of substituted phthalocyaninatozinc[J]. Spectroscopy and Spectral Analysis,2007,27(5):953-956. |
| APA | X. L. Zhu,X. Z. Xu,L. Yang,M. J. Lin,J. D. Wang,&J. L. Huang.(2007).Synthesis and photophysical properties of two kinds of substituted phthalocyaninatozinc.Spectroscopy and Spectral Analysis,27(5),953-956. |
| MLA | X. L. Zhu,et al."Synthesis and photophysical properties of two kinds of substituted phthalocyaninatozinc".Spectroscopy and Spectral Analysis 27.5(2007):953-956. |
入库方式： OAI收割
来源：福建物质结构研究所
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