Reaction of Mo(CO)(6) with alkoxide: Synthesis and structure of the Mo(0)-OR complex Et4N (3) Mo-2(CO)(6)(mu-OC6H4OCH2C6H5)(3)
文献类型：期刊论文
| 作者 | B. T. Zhuang ; Q. Wei ; L. J. He ; Z. F. Zhou ; K. C. Wu |
| 刊名 | Chinese Journal of Structural Chemistry
 |
| 出版日期 | 2007 |
| 卷号 | 26期号:4页码:401-408 |
| 关键词 | Mo(0)-OR compounds triangular bi-pyramidal core synthesis and structure formation pathway iron-molybdenum cofactor ray crystal-structure s clusters carbonyl dinuclear mo nitrogenase electrochemistry chemistry spectra |
| ISSN号 | 0254-5861 |
| 中文摘要 | The reaction of molybdenum hexacarbonyl with C6H5CH2OC6H4ONa and Et4NBr in CH3CN at 60 degrees C afforded the di-nuclear Mo(0) compound [Et4N]3[MO2(CO)6(,mu-OC6H4OCH2-C6H5)(3)] 1.1 crystallizes in monoclinic, space group P2(l)/c with a = 15.359(2), b = 18.378(3), c = 24.952(2) angstrom, beta = 102.268(4)degrees, V = 6882.3(16) angstrom(3), M-r = 1348.34, Z = 4, D-c = 1.301 g/cm(3), F(000) = 2832 and mu = 0.424 mm(-1). The final R = 0.0606 and wR = 0.1552 for 9396 observed reflections (I > 2 sigma(I)). 1 contains a [Mo2O3](3-) core in triangular bi-pyramidal configuration and each Mo atom adopts a distorted octahedral geometry with three carbon atoms from carbonyls and three mu-O atoms from C6H5CH2OC6H4O- bridging ligands. The Mo center dot center dot center dot Mo distance is 3.30(g) angstrom, indicating no metal-metal bonding. A fort-nation pathway via forming a di-molybdenum(0) di-bridging OR compound [Mo-2(mu-OR)(2)(CO)(8)](2)- has been figured out and the reaction of Mo(CO)(6) with alkoxide has also been discussed. |
| 语种 | 英语 |
| 公开日期 | 2013-04-01 |
| 源URL | [http://ir.fjirsm.ac.cn/handle/350002/6961]  |
| 专题 | 福建物质结构研究所_中科院福建物质结构研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | B. T. Zhuang,Q. Wei,L. J. He,et al. Reaction of Mo(CO)(6) with alkoxide: Synthesis and structure of the Mo(0)-OR complex Et4N (3) Mo-2(CO)(6)(mu-OC6H4OCH2C6H5)(3)[J]. Chinese Journal of Structural Chemistry,2007,26(4):401-408. |
| APA | B. T. Zhuang,Q. Wei,L. J. He,Z. F. Zhou,&K. C. Wu.(2007).Reaction of Mo(CO)(6) with alkoxide: Synthesis and structure of the Mo(0)-OR complex Et4N (3) Mo-2(CO)(6)(mu-OC6H4OCH2C6H5)(3).Chinese Journal of Structural Chemistry,26(4),401-408. |
| MLA | B. T. Zhuang,et al."Reaction of Mo(CO)(6) with alkoxide: Synthesis and structure of the Mo(0)-OR complex Et4N (3) Mo-2(CO)(6)(mu-OC6H4OCH2C6H5)(3)".Chinese Journal of Structural Chemistry 26.4(2007):401-408. |
入库方式： OAI收割
来源：福建物质结构研究所
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