中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Hybridization of polymeric micelles in a dispersion mixture

文献类型:期刊论文

作者Cai P(蔡平) ; Wang CQ(王成清) ; Ye J(叶静) ; Xie ZW(谢作伟) ; Wu Q(吴奇)
刊名Macromolecules
出版日期2004
卷号37期号:9页码:3438-3443
ISSN号0024-9297
其他题名聚合物胶束混合体系中的杂化研究
通讯作者谢作伟 ; 吴奇
英文摘要In a selective solvent, n-hexane, diblock coil-rod-like copolymers poly(ferrocenyldimethylsilane-block-dimethylsiloxane) (PFS-b-PDMS) can form spherical core-shell polymer micelles with an insoluble and aggregated PFS core and a soluble swollen PDMS shell. The micelles become larger with an increasing PFS content. The mixture of two dispersions made of PFS138-b-PDMS702 and PFS235-b-PDMS837 results in hybridization of these two kinds of block copolymer chains. The hybridization kinetics was studied by a combination of static and dynamic laser light scattering. As soon as the two micelle dispersions were mixed, larger hybrid micelles made of PFS138-b-PDMS702 and PFS235-b-PDMS837 were formed at the expense of each kind of the "pure" micelles. The hybridization can be attributed to the entropy gain as well as the space filling because the PFS block is rigid and rodlike.
学科主题高分子化学
收录类别SCI
原文出处http://dx.doi.org/10.1021/ma0352936
语种英语
WOS记录号WOS:000221190000044
公开日期2013-04-11
源URL[http://202.127.28.38/handle/331003/25305]  
专题上海有机化学研究所_上海有机化学研究所
推荐引用方式
GB/T 7714
Cai P,Wang CQ,Ye J,et al. Hybridization of polymeric micelles in a dispersion mixture[J]. Macromolecules,2004,37(9):3438-3443.
APA 蔡平,王成清,叶静,谢作伟,&吴奇.(2004).Hybridization of polymeric micelles in a dispersion mixture.Macromolecules,37(9),3438-3443.
MLA 蔡平,et al."Hybridization of polymeric micelles in a dispersion mixture".Macromolecules 37.9(2004):3438-3443.

入库方式: OAI收割

来源:上海有机化学研究所

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