Hybridization of polymeric micelles in a dispersion mixture
文献类型：期刊论文
| 作者 | Cai P(蔡平) ; Wang CQ(王成清) ; Ye J(叶静) ; Xie ZW(谢作伟) ; Wu Q(吴奇) |
| 刊名 | Macromolecules
 |
| 出版日期 | 2004 |
| 卷号 | 37期号:9页码:3438-3443 |
| ISSN号 | 0024-9297 |
| 其他题名 | 聚合物胶束混合体系中的杂化研究 |
| 通讯作者 | 谢作伟 ; 吴奇 |
| 英文摘要 | In a selective solvent, n-hexane, diblock coil-rod-like copolymers poly(ferrocenyldimethylsilane-block-dimethylsiloxane) (PFS-b-PDMS) can form spherical core-shell polymer micelles with an insoluble and aggregated PFS core and a soluble swollen PDMS shell. The micelles become larger with an increasing PFS content. The mixture of two dispersions made of PFS138-b-PDMS702 and PFS235-b-PDMS837 results in hybridization of these two kinds of block copolymer chains. The hybridization kinetics was studied by a combination of static and dynamic laser light scattering. As soon as the two micelle dispersions were mixed, larger hybrid micelles made of PFS138-b-PDMS702 and PFS235-b-PDMS837 were formed at the expense of each kind of the "pure" micelles. The hybridization can be attributed to the entropy gain as well as the space filling because the PFS block is rigid and rodlike. |
| 学科主题 | 高分子化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1021/ma0352936 |
| 语种 | 英语 |
| WOS记录号 | WOS:000221190000044 |
| 公开日期 | 2013-04-11 |
| 源URL | [http://202.127.28.38/handle/331003/25305]  |
| 专题 | 上海有机化学研究所_上海有机化学研究所 |
| 推荐引用方式 GB/T 7714 | Cai P,Wang CQ,Ye J,et al. Hybridization of polymeric micelles in a dispersion mixture[J]. Macromolecules,2004,37(9):3438-3443. |
| APA | 蔡平,王成清,叶静,谢作伟,&吴奇.(2004).Hybridization of polymeric micelles in a dispersion mixture.Macromolecules,37(9),3438-3443. |
| MLA | 蔡平,et al."Hybridization of polymeric micelles in a dispersion mixture".Macromolecules 37.9(2004):3438-3443. |
入库方式： OAI收割
来源：上海有机化学研究所
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