Synthesis of monofluorinated indolizines and their derivatives by the 1,3-dipolar reaction of N-ylides with fluorinated vinyl tosylates
文献类型:期刊论文
作者 | Fang X(方向) ; Wu YM(吴永明) ; Deng J(邓娟) ; Wang SW(王绍武) |
刊名 | Tetrahedron |
出版日期 | 2004 |
卷号 | 60期号:25页码:5487-5493 |
ISSN号 | 0040-4020 |
其他题名 | 通过氮叶立得和氟代乙烯基对甲苯磺酸酯的1,3-偶极加成反应合成单氟代中氮茚及其衍生物 |
通讯作者 | 吴永明 ; 王绍武 |
英文摘要 | Monofluorinated indolizines 4, benzo[d]indolizines 7 and 4H-pyrrolo[1,2-a]benzimidazoles 8 were synthesized in moderate yields by 1,3-dipolar reaction between fluorinated vinyl tosylates 2a and N-ylides of pyridinium, isoquinolinium and benzimidazolinium, generated in situ from their halides salts. When the same N-ylides were allowed to react with 2,3,3-trifluoro-1-propenyl tosylate 2b, the unexpected product formylated indolizines and their derivatives 9 were obtained. The reaction mechanism is also proposed. (C) 2004 Elsevier Ltd. All rights reserved. |
学科主题 | 氟化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1016/j.tet.2004.04.012 |
语种 | 英语 |
WOS记录号 | WOS:000221919500024 |
公开日期 | 2013-04-10 |
源URL | [http://202.127.28.38/handle/331003/25121] |
专题 | 上海有机化学研究所_中科院有机氟化学重点实验室 |
推荐引用方式 GB/T 7714 | Fang X,Wu YM,Deng J,et al. Synthesis of monofluorinated indolizines and their derivatives by the 1,3-dipolar reaction of N-ylides with fluorinated vinyl tosylates[J]. Tetrahedron,2004,60(25):5487-5493. |
APA | 方向,吴永明,邓娟,&王绍武.(2004).Synthesis of monofluorinated indolizines and their derivatives by the 1,3-dipolar reaction of N-ylides with fluorinated vinyl tosylates.Tetrahedron,60(25),5487-5493. |
MLA | 方向,et al."Synthesis of monofluorinated indolizines and their derivatives by the 1,3-dipolar reaction of N-ylides with fluorinated vinyl tosylates".Tetrahedron 60.25(2004):5487-5493. |
入库方式: OAI收割
来源:上海有机化学研究所
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