Monoalkyl and monoanilide yttrium complexes containing tridentate pyridyl-1-azaallyl dianionic ligands
文献类型：期刊论文
| 作者 | Lu EL(陆而立) ; Gan W(甘伟) ; Chen YF(陈耀峰) |
| 刊名 | Dalton Trans.
 |
| 出版日期 | 2011 |
| 卷号 | 40期号:10页码:2366-2374 |
| ISSN号 | 1477-9226 |
| 其他题名 | 含吡啶基-1-氮杂烯丙基三齿双阴离子配体的钇的单烷基和单胺基配合物 |
| 通讯作者 | 陈耀峰 |
| 英文摘要 | A series of pyridyl-1-azaallyl ligand precursors (HL1-HL5) were synthesized via condensation of pyridine ketones with anilines. The alkane elimination reactions between Y(CH2SiMe3)(3)(THF)(2) and HL4 or HL5 gave the monoalkyl complexes (L4-H)YCH2SiMe3(THF) (1) and (L5-H)YCH2SiMe3- (THF) (2) supported by new tridentate pyridyl-1-azaallyl dianionic ligands. The reactions of monoalkyl complexes, 1 and 2, with one equivalent of 2,6-diisopropylaniline produced the corresponding monoanilide complexes, (L4-H)YNHAr(THF) (3) and (L5-H) YNHAr(THF) (4) (Ar = 2,6-(Pr-i)(2)(CH3)-H-6), via highly selective protonolysis of the terminal alkyl Y-CH2SiMe3 bond. Complexes 1-4 are active for intramolecular hydroamination of aminoalkenes. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1039/c0dt01539c |
| 语种 | 英语 |
| WOS记录号 | WOS:000287665000039 |
| 公开日期 | 2013-04-11 |
| 源URL | [http://202.127.28.38/handle/331003/25337]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Lu EL,Gan W,Chen YF. Monoalkyl and monoanilide yttrium complexes containing tridentate pyridyl-1-azaallyl dianionic ligands[J]. Dalton Trans.,2011,40(10):2366-2374. |
| APA | 陆而立,甘伟,&陈耀峰.(2011).Monoalkyl and monoanilide yttrium complexes containing tridentate pyridyl-1-azaallyl dianionic ligands.Dalton Trans.,40(10),2366-2374. |
| MLA | 陆而立,et al."Monoalkyl and monoanilide yttrium complexes containing tridentate pyridyl-1-azaallyl dianionic ligands".Dalton Trans. 40.10(2011):2366-2374. |
入库方式： OAI收割
来源：上海有机化学研究所
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