Yttrium Anilido Hydride: Synthesis, Structure, and Reactivity
文献类型：期刊论文
| 作者 | Lu EL(陆而立) ; Chen YF(陈耀峰) ; Leng XB(冷雪冰) |
| 刊名 | Organometallics
 |
| 出版日期 | 2011 |
| 卷号 | 30期号:20页码:5433-5441 |
| ISSN号 | 0276-7333 |
| 其他题名 | 钇的胺基氢化物: 合成, 结构, 及反应性能 |
| 通讯作者 | 陈耀峰 |
| 英文摘要 | The synthesis, structure, and reactivity of the yttrium anilido hydride [LY(NH(DIPP))(mu-H)](2) (3; L = [MeC(N(DIPP))CHC(Me)(NCH(2)CH(2)NMe(2))](-), DIPP = 2,6-(i)Pr(2)C(6)H(3))) are reported. The protonolysis reaction of the yttrium dialkyl [LY(CH(2)SiMe(3))(2)] (1) with 1 equiv of 2,6-diisopropylaniline gave the yttrium anilido alkyl [LY(NH(DIPP))-(CH(2)SiMe(3))] (2), and a subsequent sigma-bond metathesis reaction of 2 with 1 equiv of PhSiH(3) offered the yttrium anilido hydride 3. The structure of 3 was characterized by X-ray crystallography, which showed that the complex is a mu-H dimer. 3 shows high reactivity toward a variety of unsaturated substrates, including imine, azobenzene, carbodiimide, isocyanide, ketone, and Mo(CO)(6), giving some structurally intriguing products. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1021/om200651c |
| 语种 | 英语 |
| WOS记录号 | WOS:000295817400015 |
| 公开日期 | 2013-04-11 |
| 源URL | [http://202.127.28.38/handle/331003/25347]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Lu EL,Chen YF,Leng XB. Yttrium Anilido Hydride: Synthesis, Structure, and Reactivity[J]. Organometallics,2011,30(20):5433-5441. |
| APA | 陆而立,陈耀峰,&冷雪冰.(2011).Yttrium Anilido Hydride: Synthesis, Structure, and Reactivity.Organometallics,30(20),5433-5441. |
| MLA | 陆而立,et al."Yttrium Anilido Hydride: Synthesis, Structure, and Reactivity".Organometallics 30.20(2011):5433-5441. |
入库方式： OAI收割
来源：上海有机化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。