Improving the nanoscale morphology and processibility for PCDTBT-based polymer solar cells via solvent mixtures
文献类型：期刊论文
| 作者 | Fang G ; Liu J ; Fu YY ; Meng B ; Zhang BH ; Xie ZY ; Wang LX |
| 刊名 | organic electronics
 |
| 出版日期 | 2012 |
| 卷号 | 13期号:11页码:2733-2740 |
| 关键词 | LOW-BANDGAP POLYMER PHOTOVOLTAIC CELLS EFFICIENCY ENHANCEMENT NETWORK |
| ISSN号 | 1566-1199 |
| 通讯作者 | xie zy |
| 中文摘要 | the effect of solvent mixtures on the morphologies of poly[n-9'-hepta-decanyl-2,7-carbazole-alt-5,5-(4',7'-di-2-thienyl-2',1',3'-benzothiadiazole)] (pcdtbt):[6,6]-phenyl c-71-butyric acid methyl ester (pc71bm) blend films is investigated. 1,2,4-trichlorobenzene (tcb) which is a good solvent for pcdtbt is selected to mix with chloroform (cf), chlorobenzene (cb) and o-dichlorobenzene (odcb) for tuning the morphology of the pcdtbt:pc71bm blend. it is found that formation of nanoscale phase separation with a fibrillar pcdtbt nanostructure of pcdtbt:pc71bm blend which is favorable for exciton separation and charge carrier transport is strongly dependent on the solubility parameters of the solvent mixtures. a clearly defined nanoscale phase separation of the pcdtbt:pc71bm blend can be obtained with tcb:cf mixture. the resulted morphology is similar to that produced with sole dcb solvent that is currently the best solvent for pcdtbt:pc71bm blend solar cells. moreover, the tcb:cf mixture demonstrates better solubility and processibility for pcdtbt:pc71bm blend and allows us to prepare thick active layer that is required in large-area roll-to-roll process. the polymer solar cells with 250 nm- thick active layer are fabricated by using tcb:cf solvent mixture and the power conversion efficiency of the devices reaches 6.45%. a highest short-circuit current of 13.6 ma/cm(2) is achieved due to enhanced optical absorption of thick active layer. (c) 2012 elsevier b.v. all rights reserved. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000311177700075 |
| 公开日期 | 2013-04-22 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/47870]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Fang G,Liu J,Fu YY,et al. Improving the nanoscale morphology and processibility for PCDTBT-based polymer solar cells via solvent mixtures[J]. organic electronics,2012,13(11):2733-2740. |
| APA | Fang G.,Liu J.,Fu YY.,Meng B.,Zhang BH.,...&Wang LX.(2012).Improving the nanoscale morphology and processibility for PCDTBT-based polymer solar cells via solvent mixtures.organic electronics,13(11),2733-2740. |
| MLA | Fang G,et al."Improving the nanoscale morphology and processibility for PCDTBT-based polymer solar cells via solvent mixtures".organic electronics 13.11(2012):2733-2740. |
入库方式： OAI收割
来源：长春应用化学研究所
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