Electrochemical sensing platform based on Schiff-base cobalt(II)/single-walled carbon nanohorns complexes system
文献类型：期刊论文
| 作者 | Lu BP ; Zhang Z ; Hao JH ; Xu GB ; Zhang BL ; Tang JL |
| 刊名 | analytical methods
 |
| 出版日期 | 2012 |
| 卷号 | 4期号:11页码:3580-3585 |
| 关键词 | MODIFIED ELECTRODE PURIFICATION ADSORPTION NANOTUBES OXIDATION |
| ISSN号 | 1759-9660 |
| 通讯作者 | tang jl |
| 中文摘要 | single-walled carbon nanohorns (swnhs), distinguished by their high purity and unique structure, were noncovalently functionalized with schiff-base cobalt(ii) (co-salen) for the first time. cyclic voltammogram of co-salen/swnhs display a pair of redox peaks with a formal potential of +0.15 v in 0.1 m phosphate buffer solution (ph 7.0). a novel bifunctional electrochemical sensor for hydrazine oxidation and hydrogen peroxide reduction are presented based on the composite modified electrode. using amperometry, the linear relationship of hydrazine was found to be in the range from 1 to 96 mu m with a sensitivity of 2.4 mu a mm(-1), the detection limit is 0.1 mu m (s/n = 3). the linear relationship of hydrogen peroxide is in the range from 50 to 4600 mu m with a sensitivity of 1.8 mu a mm(-1), the detection limit is 10 mu m (s/n = 3). the hybrid material provides a good electrochemical sensing platform and has potential applications in environment analysis and biosensors. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000310281700013 |
| 公开日期 | 2013-04-22 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/47878]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Lu BP,Zhang Z,Hao JH,et al. Electrochemical sensing platform based on Schiff-base cobalt(II)/single-walled carbon nanohorns complexes system[J]. analytical methods,2012,4(11):3580-3585. |
| APA | Lu BP,Zhang Z,Hao JH,Xu GB,Zhang BL,&Tang JL.(2012).Electrochemical sensing platform based on Schiff-base cobalt(II)/single-walled carbon nanohorns complexes system.analytical methods,4(11),3580-3585. |
| MLA | Lu BP,et al."Electrochemical sensing platform based on Schiff-base cobalt(II)/single-walled carbon nanohorns complexes system".analytical methods 4.11(2012):3580-3585. |
入库方式： OAI收割
来源：长春应用化学研究所
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