Donor-Induced Helical Inversion of 1,1 '-Binaphthyl Connecting with Two Molybdenum Complexes
文献类型：期刊论文
| 作者 | Ma L ; Jin RZ ; Bian Z ; Kang CQ ; Chen Y ; Xu JW ; Gao LX |
| 刊名 | chemistry-a european journal
 |
| 出版日期 | 2012 |
| 卷号 | 18期号:41页码:13168-13172 |
| 关键词 | CONFORMATIONAL-ANALYSIS CIRCULAR-DICHROISM COBALT(II) COMPLEX CHIRALITY SWITCH COORDINATION SPECTROSCOPY INDUCTION PROPELLER BEHAVIOR CYSTEINE |
| ISSN号 | 0947-6539 |
| 通讯作者 | bian z |
| 中文摘要 | an atropisomeric biaryl molecule with a given absolute configuration could present two opposite helical conformations through the rotation around c?c single bond. to the best of our knowledge, the biaryl system is the simplest helical inversion model apart from stereomutation between two enantiomers. herein, we first report such true helical inversion phenomena of biaryl compounds. two [movio2(l)]-type complexes, in which l is a tridentate dioxoanionic pyridine o,n,o-ligand, are coalesced on the 2,2',3,3'-positions of an (r)-1,1'-binaphthyl unit and an intramolecular dioxo bridge is formed by two mo?o center dot center dot center dot mo interactions. exterior strong donors can coordinate to molybdenum to interrupt this dioxo bridge and inversions from negative to positive chirality are explicitly observed by circular dichroism spectroscopy, consistent with single-crystal x-ray diffraction analyses. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000309239300032 |
| 公开日期 | 2013-04-23 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/47920]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Ma L,Jin RZ,Bian Z,et al. Donor-Induced Helical Inversion of 1,1 '-Binaphthyl Connecting with Two Molybdenum Complexes[J]. chemistry-a european journal,2012,18(41):13168-13172. |
| APA | Ma L.,Jin RZ.,Bian Z.,Kang CQ.,Chen Y.,...&Gao LX.(2012).Donor-Induced Helical Inversion of 1,1 '-Binaphthyl Connecting with Two Molybdenum Complexes.chemistry-a european journal,18(41),13168-13172. |
| MLA | Ma L,et al."Donor-Induced Helical Inversion of 1,1 '-Binaphthyl Connecting with Two Molybdenum Complexes".chemistry-a european journal 18.41(2012):13168-13172. |
入库方式： OAI收割
来源：长春应用化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。