Efficient one-pot synthesis of molecularly imprinted silica nanospheres embedded carbon dots for fluorescent dopamine optosensing
文献类型:期刊论文
作者 | Mao Y ; Bao Y ; Han DX ; Li FH ; Niu L |
刊名 | biosensors & bioelectronics
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出版日期 | 2012 |
卷号 | 38期号:1页码:55-60 |
关键词 | QUANTUM DOTS POLYMER WATER NANOPARTICLES COMPOSITE SENSOR |
ISSN号 | 0956-5663 |
通讯作者 | han dx |
中文摘要 | a new type of eco-friendly molecularly imprinted polymer (mip) was synthesized through an efficient one-pot room-temperature sol-gel polymerization and applied as a molecular recognition element to construct dopamine (da) fluorescence (fl) optosensor. highly luminescent carbon dots (cds) were firstly synthesized via a one-step reaction in organosilane, and their surface were anchored with mip matrix (cds@mip). the resulting composite of a synergetic combination of cds with mip showed high photostability and template selectivity. moreover, the composite allowed a highly sensitive determination of da via fl intensity decreasing when removal of the original templates. the new mip-based da sensing protocol was applied to detect da concentration in aqueous solution, the relative fl intensity of cds@mip decreased linearly with the increasing da in the concentration range of 25-500 nm with a detection limit (3 sigma) of 1.7 nm. furthermore, the proposed method was successfully intended for the determination of trace da in human urine samples without the interference of other molecules and ions. (c) 2012 elsevier b.v. all rights reserved. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000308455700009 |
公开日期 | 2013-04-23 |
源URL | [http://ir.ciac.jl.cn/handle/322003/47924] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Mao Y,Bao Y,Han DX,et al. Efficient one-pot synthesis of molecularly imprinted silica nanospheres embedded carbon dots for fluorescent dopamine optosensing[J]. biosensors & bioelectronics,2012,38(1):55-60. |
APA | Mao Y,Bao Y,Han DX,Li FH,&Niu L.(2012).Efficient one-pot synthesis of molecularly imprinted silica nanospheres embedded carbon dots for fluorescent dopamine optosensing.biosensors & bioelectronics,38(1),55-60. |
MLA | Mao Y,et al."Efficient one-pot synthesis of molecularly imprinted silica nanospheres embedded carbon dots for fluorescent dopamine optosensing".biosensors & bioelectronics 38.1(2012):55-60. |
入库方式: OAI收割
来源:长春应用化学研究所
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