Two 3D Supramolecular Isomeric Mixed-Ligand CoII Frameworks - Guest-Induced Structural Variation, Magnetism, and Selective Gas Adsorption
文献类型：期刊论文
| 作者 | Liu D ; Liu YX ; Xu GH ; Li GH ; Yu Y ; Wang C |
| 刊名 | european journal of inorganic chemistry
 |
| 出版日期 | 2012 |
| 期号 | 28页码:4413-4417 |
| 关键词 | METAL-ORGANIC FRAMEWORK NANOPOROUS COORDINATION FRAMEWORK ORDERING TEMPERATURE SPIN-CROSSOVER POROUS MAGNET TRANSFORMATION ARCHITECTURE CONVERSION COBALT(II) COMPOUND |
| ISSN号 | 1434-1948 |
| 通讯作者 | wang c |
| 中文摘要 | two 3d supramolecular isomers with composition co2(bdc)2(bpno) (bpno = 4,4'-bipyridyl n,n'-dioxide, bdc = 1,4-benzenedicarboxylic acid) were prepared by using mixed ligands in different solvents. the two compounds are built up from different infinite chains of corner-sharing coo6 octahedra. in compound 1, 2d cobdc layers are pillared by neutral bpno to form a 3d framework, while in compound 2, the interconnection between the zig-zag coo chains and two organic moieties leads to a co-based mil-53 analogue containing 1d nanosized rhombic channels. compound 1 is a weak ferromagnet with two field-induced magnetic transitions, and compound 2 displays antiferromagnetic interactions. furthermore, compound 1 shows a typical solvatomagnetic effect and its desolvated compound appears to be a hidden weak ferromagnet with two field-induced magnetic transitions. the structural variation between compounds 1 and 2 is ascribed to the different hostguest interactions within the two compounds and is believed to be responsible for the difference in the magnetic properties. as a result of their identical framework composition, compounds 1 and 2, after removal of the guest molecules, exhibited similar gas adsorption behavior. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000309063300003 |
| 公开日期 | 2013-04-23 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/47929]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Liu D,Liu YX,Xu GH,et al. Two 3D Supramolecular Isomeric Mixed-Ligand CoII Frameworks - Guest-Induced Structural Variation, Magnetism, and Selective Gas Adsorption[J]. european journal of inorganic chemistry,2012(28):4413-4417. |
| APA | Liu D,Liu YX,Xu GH,Li GH,Yu Y,&Wang C.(2012).Two 3D Supramolecular Isomeric Mixed-Ligand CoII Frameworks - Guest-Induced Structural Variation, Magnetism, and Selective Gas Adsorption.european journal of inorganic chemistry(28),4413-4417. |
| MLA | Liu D,et al."Two 3D Supramolecular Isomeric Mixed-Ligand CoII Frameworks - Guest-Induced Structural Variation, Magnetism, and Selective Gas Adsorption".european journal of inorganic chemistry .28(2012):4413-4417. |
入库方式： OAI收割
来源：长春应用化学研究所
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