Solution-Processed Double-Silicon-Bridged Oxadiazole/Arylamine Hosts for High-Efficiency Blue Electrophosphorescence
文献类型：期刊论文
| 作者 | Gong SL ; Fu Q ; Zeng WX ; Zhong C ; Yang CL ; Ma DG ; Qin JG |
| 刊名 | chemistry of materials
 |
| 出版日期 | 2012 |
| 卷号 | 24期号:16页码:3120-3127 |
| 关键词 | LIGHT-EMITTING DEVICES ELECTRON-TRANSPORT MATERIALS RED PHOSPHORESCENT OLEDS ORGANIC ELECTROPHOSPHORESCENCE BIPOLAR HOST ROLL-OFF GREEN ELECTROPHOSPHORESCENCE DIODES CARBAZOLE MOLECULE |
| ISSN号 | 0897-4756 |
| 通讯作者 | yang cl |
| 中文摘要 | a series of oxadiazole/arylamine hybrids, namely poxddsipa, poxddsicz, moxddsipa, and moxddsicz, were designed and synthesized by incorporating electron donating diphenylamine or 3,6-di-tert-butyl-9h-carbazole unit and electron accepting oxadiazole moiety into one molecule via double-silicon-bridged linkage. this design strategy of extending molecular structure endows these compounds with good solution processability, and high thermal and morphological stability, without lowering their triplet energies. these compounds exhibit similar energy levels and higher glass transition temperatures (92-190 degrees c) relative to the corresponding single-silicon-bridged congeners. the reasonable combination of the tetra-meta-position linking topology and electron donor diphenylamine group imparts the. compound moxddsipa with both relative high triplet energy (2.72 ev) and high lying homo level (5.30 ev). as a result, the best el performance was achieved for the moxddsipa-based blue phosphorescent device, with a maximum current efficiency of 23.4 cd a(-1), a maximum power efficiency of 10.2 lm w-1, and a maximum external quantum efficiency of 10.7%. moreover, the current efficiency remains as high as 23.3 cd a(-1) at the luminance of 100 cd m(-2), and even at the high luminance of 1000 cd m(-2), the efficiency is still 17.7 cd a(-1). |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000307988800004 |
| 公开日期 | 2013-04-23 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/47987]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Gong SL,Fu Q,Zeng WX,et al. Solution-Processed Double-Silicon-Bridged Oxadiazole/Arylamine Hosts for High-Efficiency Blue Electrophosphorescence[J]. chemistry of materials,2012,24(16):3120-3127. |
| APA | Gong SL.,Fu Q.,Zeng WX.,Zhong C.,Yang CL.,...&Qin JG.(2012).Solution-Processed Double-Silicon-Bridged Oxadiazole/Arylamine Hosts for High-Efficiency Blue Electrophosphorescence.chemistry of materials,24(16),3120-3127. |
| MLA | Gong SL,et al."Solution-Processed Double-Silicon-Bridged Oxadiazole/Arylamine Hosts for High-Efficiency Blue Electrophosphorescence".chemistry of materials 24.16(2012):3120-3127. |
入库方式： OAI收割
来源：长春应用化学研究所
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