Au@Pd core-shell nanoparticles: A highly active electrocatalyst for amperometric gaseous ethanol sensors
文献类型:期刊论文
作者 | Li CL ; Su Y ; Lv XY ; Zuo YY ; Yang XG ; Wang YJ |
刊名 | sensors and actuators b-chemical
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出版日期 | 2012 |
卷号 | 171页码:1192-1198 |
关键词 | SOLID POLYMER ELECTROLYTE ALKALINE MEDIA OXIDATION PALLADIUM CATALYSIS GOLD ELECTROOXIDATION NANOCATALYSTS NANOWIRES ALCOHOLS |
ISSN号 | 0925-4005 |
通讯作者 | su y |
中文摘要 | au@pd core-shell nanoparticles (nps) were synthesized using seed-mediated method, and three samples with different shell structures were obtained by tuning the au core size. the shape-dependent catalytic activities of au@pd core-shell nps toward ethanol oxidation in alkaline electrolytes were systematically explored. the electrochemical experiments showed that the au@pd-2 core-shell nps (with au core size of 9.8 nm and loose pd shell) exhibited a distinctly higher activity and poison-resistance for the ethanol oxidation than other core-shell structures. based on the au@pd-2 core-shell nps and pd nps, two amperometric ethanol gas sensors were fabricated. during the sensor tests, the ethanol sensor based on au@pd-2 nps showed good performance for ethanol in the range of 50-600 ppm with sensitivity of 178.5 na ppm(-1) and less than 5% signal loss in 60 days. 2012 published by elsevier b.v. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000308572700158 |
公开日期 | 2013-04-23 |
源URL | [http://ir.ciac.jl.cn/handle/322003/48020] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Li CL,Su Y,Lv XY,et al. Au@Pd core-shell nanoparticles: A highly active electrocatalyst for amperometric gaseous ethanol sensors[J]. sensors and actuators b-chemical,2012,171:1192-1198. |
APA | Li CL,Su Y,Lv XY,Zuo YY,Yang XG,&Wang YJ.(2012).Au@Pd core-shell nanoparticles: A highly active electrocatalyst for amperometric gaseous ethanol sensors.sensors and actuators b-chemical,171,1192-1198. |
MLA | Li CL,et al."Au@Pd core-shell nanoparticles: A highly active electrocatalyst for amperometric gaseous ethanol sensors".sensors and actuators b-chemical 171(2012):1192-1198. |
入库方式: OAI收割
来源:长春应用化学研究所
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