A novel Bi-doped borosilicate glass as sealant for sodium sulfur battery. Part 1: Thermophysical characteristics and structure
文献类型：期刊论文
| 作者 | Song SF(宋树丰) ; Wen ZY(温兆银) ; Zhang QX(张群喜) ; Liu Y(刘宇) |
| 刊名 | JOURNAL OF POWER SOURCES
 |
| 出版日期 | 2009-09-24 |
| 卷号 | 195期号:1页码:384-388 |
| ISSN号 | 0378-7753 |
| 其他题名 | A novel Bi-doped borosilicate glass as sealant for sodium sulfur battery. Part 1: Thermophysical characteristics and structure |
| 通讯作者 | 温兆银 |
| 中文摘要 | A novel Bi-doped borosilicate glass has been developed as sealant for sodium sulfur battery. The thermophysical characteristics like thermal expansion coefficient, glass transition and softening temperatures, viscosities and densities of the Bi-doped and undoped glasses are systematically studied. It is found that the thermal expansion match between the Bi-doped glasses and alpha-alumina/ beta-alumina is satisfactory. The Bi-doped glass has a viscosity around 10(5) Pa s in 800-850 degrees C range, which is suitable to allow a good bonding with the sealed parts. The FTIR analysis indicates that the substitution of Bi2O3 for SiO2 makes the glass network less rigid. Bi2O3 builds the glass network as [BiO6] unit. [BO4] unit enters the glass network and induces the overlapped vibrations of [BO4] unit and [SiO4] tetrahedron. The Bi-doped glass sealant exhibits superior chemical compatibility with alpha-alumina and beta-alumina. (C) 2009 Elsevier B. V. All rights reserved. |
| 学科主题 | 玻璃与非晶无机非金属材料 |
| 收录类别 | SCI收录 |
| 原文出处 | http://apps.isiknowledge.com/full_record.do?product=UA&search_mode=GeneralSearch&qid=1&SID=Y1kf83B76nm@hCHiHI6&page=1&doc=1&colname=WOS |
| WOS记录号 | WOS:000272883200056 |
| 公开日期 | 2012-07-02 |
| 源URL | [http://ir.sic.ac.cn/handle/331005/705]  |
| 专题 | 上海硅酸盐研究所_能量转换材料重点实验室_期刊论文 |
| 推荐引用方式 GB/T 7714 | Song SF,Wen ZY,Zhang QX,et al. A novel Bi-doped borosilicate glass as sealant for sodium sulfur battery. Part 1: Thermophysical characteristics and structure[J]. JOURNAL OF POWER SOURCES,2009,195(1):384-388. |
| APA | 宋树丰,温兆银,张群喜,&刘宇.(2009).A novel Bi-doped borosilicate glass as sealant for sodium sulfur battery. Part 1: Thermophysical characteristics and structure.JOURNAL OF POWER SOURCES,195(1),384-388. |
| MLA | 宋树丰,et al."A novel Bi-doped borosilicate glass as sealant for sodium sulfur battery. Part 1: Thermophysical characteristics and structure".JOURNAL OF POWER SOURCES 195.1(2009):384-388. |
入库方式： OAI收割
来源：上海硅酸盐研究所
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