Effect of Ta-doping on the ionic conductivity of lithium titanate
文献类型:期刊论文
作者 | Wu XW(吴相伟) ; Wen ZY(温兆银) ; Wang XY(王秀艳) ; Xu XG(徐小刚) ; Lin J(林久) ; Song SF(宋树丰) |
刊名 | Fusion Engineering and Design
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出版日期 | 2010-05-14 |
卷号 | 85期号:7页码:1442-1445 |
ISSN号 | 0920-3796 |
其他题名 | Effect of Ta-doping on the ionic conductivity of lithium titanate |
通讯作者 | 温兆银 |
中文摘要 | The powders of Li2Ti1?xTaxO3+x/2 (0.10 ≤ x ≤ 0.35) were synthesized by a solid-state reaction method and Li2Ti1?xTaxO3+x/2 sintered bodies were fabricated with the powders at 1100 °C for 6 h. Phase analysis and microstructure of the samples were determined by XRD and SEM, respectively. Complex electrochemical impedance spectroscopy was used to evaluate the electrical conduction properties of the sintered ceramics. The experimental results showed that Ta2O5 could dissolve in Li2TiO3 and reached the saturation degree of about 25% at 1100 °C. The doped samples possessed much higher ionic conductivity than the primitive Li2TiO3 with the most favorable doping level of 25%. At 300 °C, the ionic conductivity of the doped Li2Ti0.75Ta0.25O3.125 (x = 0.25) ceramics achieved 9.00 × 10?5 S cm?1, more than 2 orders of magnitude higher than that of the primitive Li2TiO3 ceramics (7.75 × 10?7 S cm?1). |
学科主题 | 无机陶瓷材料 |
收录类别 | SCI收录 |
WOS记录号 | WOS:000287333200090 |
公开日期 | 2012-07-02 |
源URL | [http://ir.sic.ac.cn/handle/331005/725] ![]() |
专题 | 上海硅酸盐研究所_能量转换材料重点实验室_期刊论文 |
推荐引用方式 GB/T 7714 | Wu XW,Wen ZY,Wang XY,et al. Effect of Ta-doping on the ionic conductivity of lithium titanate[J]. Fusion Engineering and Design,2010,85(7):1442-1445. |
APA | 吴相伟,温兆银,王秀艳,徐小刚,林久,&宋树丰.(2010).Effect of Ta-doping on the ionic conductivity of lithium titanate.Fusion Engineering and Design,85(7),1442-1445. |
MLA | 吴相伟,et al."Effect of Ta-doping on the ionic conductivity of lithium titanate".Fusion Engineering and Design 85.7(2010):1442-1445. |
入库方式: OAI收割
来源:上海硅酸盐研究所
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