Surface structural analysis of electrochemically fabricated Ag quantum wire by its interactions with NH3 molecules in an aqueous environment
文献类型:期刊论文
作者 | Dong XD ; Liu JH ; Zhang BL ; Xia Y |
刊名 | electrochimica acta
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出版日期 | 2012 |
卷号 | 74页码:78-82 |
关键词 | REFLECTION ANISOTROPY SPECTROSCOPY THIN METALLIC WIRES CONDUCTANCE QUANTIZATION SILVER NANOWIRES ATOMIC-SCALE AMINE VAPOR PYRIDINE ADSORPTION ELECTRODES AU(110) |
ISSN号 | 0013-4686 |
通讯作者 | dong xd |
中文摘要 | the interactions between an electrochemically fabricated ag quantum wire and nh3 molecules in an aqueous environment were studied. the ag quantum wire showed a stepwise decrease of conductance change upon exposure to the definite concentration of nh3 molecules in an aqueous environment. similar changes were also observed when an ag quantum wire interacted with methyl amine, ethylenediamine and acetonitrile molecules, respectively. we experimentally probed the mechanism for the conductance modulation in the case of ammonia and proposed a model to describe it. the ag quantum wire showed a conductance increasing process upon addition of the chemical reduced regent, sodium borohydride or ascorbic acid. conductance increase was also seen with a process of electrochemical reduction. based on the related data, we further proposed the existing partly ag ions in the ag quantum wire surface played a key role for these changes of ag wire conductance. the work also showed the unique property of atomic-scale metal electrode different from the bulk electrode. (c) 2012 elsevier ltd. all rights reserved. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000305373000012 |
公开日期 | 2013-05-20 |
源URL | [http://ir.ciac.jl.cn/handle/322003/48044] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Dong XD,Liu JH,Zhang BL,et al. Surface structural analysis of electrochemically fabricated Ag quantum wire by its interactions with NH3 molecules in an aqueous environment[J]. electrochimica acta,2012,74:78-82. |
APA | Dong XD,Liu JH,Zhang BL,&Xia Y.(2012).Surface structural analysis of electrochemically fabricated Ag quantum wire by its interactions with NH3 molecules in an aqueous environment.electrochimica acta,74,78-82. |
MLA | Dong XD,et al."Surface structural analysis of electrochemically fabricated Ag quantum wire by its interactions with NH3 molecules in an aqueous environment".electrochimica acta 74(2012):78-82. |
入库方式: OAI收割
来源:长春应用化学研究所
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